期刊信息
期刊名称：《中国胶粘剂》CHINA ADHESIVES
创办日期：1986(1973)
主管部门：上海华谊（集团）有限公司
主办单位：上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会
刊 期：月刊
Email：GXLJ@chinajournal.net.cn
国内统一刊号(CN)：
CN 31-1601/TQ
国际标准刊号(ISSN)：
ISSN 1004-2849
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本刊介绍
《中国胶粘剂》为重点报道中国胶粘剂科研成果和最新进展的学术期刊，月刊。1973年创刊，原名为《树脂粘合剂》，1979年更名为《粘合剂》，1991年更名为《中国胶粘剂》，2014年12月，成为原国家新闻出版广电总局第一批认定学术期刊。
主管单位是上海华谊控股集团有限公司，主办单位是上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会。
期刊在国内外公开发行，国内发行代号为4-454，国外发行代号为M5121；国内统一连续出版物号为CN31-1601/TQ，国际标准连续出版物号为ISSN 1004-2849。
期刊设有专题综述、研究报告、工艺与应用、材料科学等栏目，主要报道国内外胶粘剂、密封剂和胶粘带行业的最新理论研究成果、原料/设备/制备工艺创新、粘接接头设计制备技术、生产应用实践等论文和综述等，主要涉及领域主要包括化工、轻工、包装、纺织、建筑、机械、电子、航空、航天、汽车、船舶、林木、家具和印刷等领域。
期刊为中国科技核心期刊、RCCSE中国核心学术期刊，《科技期刊世界影响力指数（WJCI）报告》收录期刊，曾为全国中文核心期刊（2007/2011/2014/2017年），现被“中国核心期刊数据库、”“中国期刊全文数据库”、“中国学术期刊综合评价数据库”、《中国学术期刊影响因子年报》统计源、美国《化学文摘》（CA）、中国知网数据库（CNKI）、万方数据库、维普数据库、新华网“学术中国”以及长江文库等收录，先后荣获《CAJ-CD规范》执行优秀期刊、全国石油和化工行业优秀期刊二等奖、全国石油和化工行业优秀期刊一等奖、华东地区优秀期刊奖、上海市科技期刊审读优秀奖、上海市期刊编校质量优秀奖、全国石油和化工学术期刊50强、全国石油和化工行业期刊100强、全国石油和化工学术期刊60强。2024年，期刊还被中国化工学会发布的首版《化工领域高质量科技期刊分级目录》入选为T3级期刊，标志着我刊已进入化工领域“国内外重要、为学术界所认可的期刊”队列。2024年期刊复合影响因子为1.595，综合影响因子为1.309。
《中国胶粘剂》杂志是胶粘剂行业的窗口，是胶粘剂企业的桥梁，是胶粘剂读者的纽带。
高效光伏电池封装材料与0BB封装技术研究进展
Research progress on encapsulation materials and 0BB encapsulation technology for high-efficiency photovoltaic cells
叶安城;李伟京;石洪涛;王伟民;裴克梅; Ye Ancheng;Li Weijing;Shi Hongtao;Wang Weimin;Pei Kemei;为支撑HJT、TOPCon及钙钛矿/晶硅叠层等高效光伏电池向高功率、低损耗、长寿命方向发展，本文综述了光伏组件封装材料的研究进展与分类特性。重点分析了4种封装胶膜，即乙烯-醋酸乙烯共聚物（EVA）、有机硅、聚烯烃弹性体（POE）及新兴的光转共挤一体膜（EPE）材料。深入讨论了主流封装材料的物理性能、优劣及应用场景。对比了SWCT、点胶、焊接点胶三种无主栅（0BB）封装技术主流工艺路线的流程、优势与技术瓶颈，并阐述了适配0BB技术的封装胶膜（皮肤膜+常规胶膜、一体膜等）的发展现状。0BB技术通过取消主栅，能够降低银浆消耗、减少遮光面积、提升组件功率并增强其抗隐裂能力，是高效电池封装的核心方向之一，但仍面临工艺复杂度高、材料成本上升、胶膜适配性不足等挑战。未来封装技术的发展将聚焦材料配方优化、0BB工艺简化与成本控制，推动封装技术与高效电池的深度融合，为光伏产业降本增效提供支撑。
To support the development of high-efficiency photovoltaic cells such as HJT,TOPCon,and perovskite/crystalline silicon tandem cells towards high power,low loss,and long lifetime,the research progress and classification characteristics of photovoltaic module encapsulation materials were summarized in this paper. Four types of encapsulation films were analyzed in details,namely ethylene-vinyl acetate copolymer(EVA),organosilicon,polyolefin elastomer(POE),and emerging light-conversion co-extruded integrated film(EPE) materials. The physical properties,advantages,disadvantages,and application scenarios of mainstream encapsulation materials were deeply discussed. The mainstream process routes,advantages,and technical bottlenecks of three kinds of busbar-free(0 BB) encapsulation technologies,such as SWCT,dispensing,and welding-dispensing were compared,and the development status of encapsulation films adapted to 0 BB technology(skin film+conventional adhesive film,integrated film,etc.) was elucidated. 0 BB technology could reduce silver paste consumption,decrease shading area,improve module power,and enhance anti-microcrack capability by eliminating busbars. It was one of the core directions for high-efficiency cell encapsulation,but still faced challenges such as high process complexity,rising material costs,and insufficient film adaptability. Future encapsulation technology development would focus on material formulation optimization,0 BB process simplification,and cost control,promoting the deep integration of encapsulation technology with high-efficiency cells,and providing support for cost reduction and efficiency improvement in the photovoltaic industry.
黏合层对陶瓷复合装甲防弹性能的影响
Effect of adhesive layer on the bulletproof performance of ceramic composite armor
姚易斌;张虹;孙志皓;林文松; Yao Yibin;Zhang Hong;Sun Zhihao;Lin Wensong;由陶瓷面板与金属或纤维复材背板黏合固化而成的复合装甲是当代轻质防弹装甲的一种主流形式。其防弹性能不仅取决于陶瓷面板与背板，黏合层也会起关键作用。本文在阐述多层复合装甲防弹机理的基础上，系统综述了黏合层的粘接强度、力学性能、声阻抗及厚度对装甲抗弹性能的影响。通过系统梳理发现，提高粘接强度可有效抑制界面分层，改善抗多发打击能力；增大弹性模量有助于提升单次抗弹效能，但会降低材料韧性；减小黏合剂与陶瓷的声阻抗失配可延缓陶瓷早期失效；黏合层厚度对防护性能呈非线性影响，存在最优区间。本文为陶瓷复合装甲用黏合剂选型及界面结构优化提供了理论参考。
Composite armor fabricated by bonding and curing ceramic panels to metal or fiber composite backplate is a mainstream form of contemporary lightweight bulletproof armor.Its bulletproof performance depends not only on the ceramic panel and backplate,but also on the adhesive layer which plays a critical role.Based on the elucidation of the bulletproof mechanism of multilayer composite armor,the effects of bonding strength,mechanical properties,acoustic impedance,and thickness of adhesive layer on the bulletproof armor were systematically reviewed in this study. Through systematic analysis,it was found that improving the bonding strength could effectively suppress interfacial delamination and enhance the multi-hit resistance;increasing the elastic modulus helped improve single-hit bulletproof effectiveness but reduced the material toughness;reducing the acoustic impedance mismatch between the adhesive and ceramic could delay the early failure of ceramics;the thickness of adhesive layer exhibited a nonlinear effect on protective performance,with an optimal range.This study provided theoretical reference for adhesive selection and interface structure optimization of ceramic composite armor.
低气味高强度双组分丙烯酸酯结构胶的制备及性能研究：基于自制聚丙烯酸酯弹性体
Preparation and performance study of low-odor high-strength two-component acrylic structural adhesive:Based on self-synthesized polyacrylate elastomers
苏开禹;黄鹤; Su Kaiyu;Huang He;双组分丙烯酸酯结构胶因综合性能优异、适用面广而被广泛应用，但传统产品普遍存在气味大、成本高的问题。为兼顾低气味与高强度，同时降低原料成本，本文以价廉易得的低气味甲基丙烯酸羟乙酯（HEMA）为稀释单体，基于相似相溶原理，自主设计合成了两类可良好溶于HEMA的聚丙烯酸酯弹性体：一类为分子链中无双键的Ⅰ型弹性体，另一类为分子链中引入双键的Ⅱ型弹性体，并分别制备了第一代（FGA）与第二代（SGA）低气味双组分丙烯酸酯结构胶。通过溶解性测试、单因素及正交试验系统考察了弹性体组成、单体种类及配比对胶粘剂性能的影响。结果表明：两类自制弹性体在HEMA中的溶解度均超过50%，显著优于氯丁橡胶、丁腈橡胶及MBS等常规弹性体；FGA胶的拉伸剪切强度最高可达20.40 MPa，与SGA胶（21～23 MPa）基本持平；优化Ⅱ型弹性体与HEMA配比后，SGA胶的拉伸剪切强度进一步提升至23.70 MPa，优于对标参照产品（22 MPa），且气味等级低、原料成本显著降低。研究证实，采用低气味HEMA搭配自制聚丙烯酸酯弹性体，可成功制备出综合性能优异的低气味高强度双组分丙烯酸酯结构胶，为该类产品的低成本化与环保化提供了新思路。
Two-component acrylate structural adhesive is widely used due to its excellent comprehensive properties and broad applicability,but traditional products generally suffer from problems of strong odor and high costs.To achieve both low odor and high strength while reducing raw material costs,low-cost and readily available low-odor 2-hydroxyethyl methacrylate(HEMA) was employed as the diluent monomer in this study,and based on the principle of similar compatibility,two types of polyacrylate elastomers that could dissolve well in HEMA were independently designed and synthesized:one was the Type Ⅰ elastomer without double bonds in the molecular chain,,and the other was the Type Ⅱ elastomer with double bonds introduced into the molecular chain and the first-generation(FGA) and second-generation(SGA) low-odor two-component acrylate structural adhesive were prepared,respectively.Through solubility tests,single-factor experiments,and orthogonal experiments,the effects of elastomer composition,monomer type,and formulation ratio on adhesive properties were systematically investigated.The research results showed that the solubility of both types of self-made elastomers in HEMA exceeded 50%,which was significantly superior to conventional elastomers such as polychloroprene rubber,nitrile rubber,and MBS.The tensile shear strength of FGA adhesive reached up to 20.40 MPa,which was basically equivalent to that of SGA adhesive(21-23 MPa).After optimizing the ratio of Type Ⅱ elastomer to HEMA,the tensile shear strength of SGA adhesive was further improved to 23.70 MPa,which was superior to the benchmarking reference product(22 MPa),and the odor level was low with significantly reduced raw material costs.This study confirmed that the use of low-odor HEMA combined with self-made polyacrylate elastomers could successfully prepare low-odor high-strength two-component acrylate structural adhesive with excellent comprehensive properties,providing new ideas for the low-cost and environmentally friendly development of such products.
生物基环氧树脂导热结构胶的制备与性能研究
Preparation and properties of bio-based epoxy thermally conductive structural adhesive
李自奇;吴梓邦;艾娇艳;宋丽娜;刘保华; Li Ziqi;Wu Zibang;Ai Jiaoyan;Song Lina;Liu Baohua;针对传统石油基环氧树脂导热系数低、生物基环氧树脂导热复合材料研究不足的问题，以自制衣康酸基环氧树脂为基体，聚酰胺650为固化剂，引入球形氧化铝(单粒径/双粒径)与改性短切碳纤维(CF)，制备了系列生物基环氧树脂导热结构胶。系统研究了填料粒径、填充量、双粒径级配及CF/Al_2O3杂化比例对导热、力学和热机械性能的影响。研究结果表明：在单一粒径填充体系中，10μm球形Al_2O3在75%填充量下可实现最高导热系数[1.06 W/(m·K)]，但韧性偏低；在双粒径级配体系中，5和10μm组合在导热系数[1.09 W/(m·K)]与冲击强度(12.32 kJ/m2)上实现了相对最优平衡，同时剪切强度(15.14 MPa)处于中等水平，综合性能优异；5和20μm组合则展现了最高的导热系数[1.11 W/(m·K)]，为基体环氧树脂[0.22 W/(m·K)]的504.55%；在碳纤维/氧化铝杂化填料体系中，添加5%CF的配方在保持高导热[1.02 W/(m·K)]的同时，剪切强度升至17.28 MPa，冲击强度升至14.83 kJ/m2，玻璃化转变温度最高(87.3℃)，固化网络完整性最好。本文揭示了多尺度填料堆积与纤维增强协同导热/增韧机制，为高性能、环保型生物基导热结构胶开发提供理论依据。
To address the problems of low thermal conductivity of conventional petroleum-based epoxy resin and insufficient research on bio-based epoxy resin thermally conductive composites,self-synthesized itaconic acidbased epoxy resin was used as the matrix and polyamide 650 as the curing agent,spherical alumina(single particle size/dual particle size) and modified chopped carbon fiber(CF) were introduced,a series of bio-based epoxy thermally conductive structural adhesive were prepared.The effects of filler particle size,filler content,dual particle size grading,and CF/Al_2O3 hybrid ratio on thermal conductivity,mechanical,and thermomechanical properties were systematically investigated.The research results showed that in the single particle size filling system,spherical Al_2O3 with 10 μm diameter achieved the highest thermal conductivity [1.06 W/(m·K)] at the filling ratio of 75%,but exhibited relatively low toughness.In the dual particle size grading system,the combination of 5 and 10 μm achieved a relatively optimal balance between thermal conductivity [1.09 W/(m·K)] and impact strength(12.32 kJ/m2),while the shear strength(15.14 MPa) was at a moderate level,demonstrating excellent comprehensive performance. The combination of 5 and 20 μm exhibited the highest thermal conductivity [1.11 W/(m·K)],which was 504.55% of the matrix epoxy resin [0.22 W/(m·K)].In the carbon fiber/alumina hybrid filler system,the formula with 5% CF added maintained high thermal conductivity [1.02 W/(m·K)] while increasing the shear strength to 17.28 MPa,impact strength to 14.83 kJ/m2,glass transition temperature to the highest(87.3 ℃),and curing network integrity was the best.This study revealed the synergistic thermal conductivity/toughening mechanism of multi-scale filler packing and fiber reinforcement,providing theoretical basis for the development of high-performance and environmentally friendly bio-based thermally conductive structural adhesive.
TGTHEIC多官能环氧-BMI胶粘剂的研制与性能研究
Development and performance study of TGTHEIC multifunctional epoxy-BMI adhesive
杨红;虞鑫海; Yang Hong;Yu Xinhai;为提高环氧树脂的韧性、耐热性及介电综合性能，拓宽其在电子封装与航空航天等领域的应用，本文以多官能团含氮杂环环氧树脂三缩水甘油基三(2-羟基乙基)异氰尿酸酯(TGTHEIC)为基体，复配环氧树脂、端羧基液体丁腈橡胶及4,4'-二氨基二苯砜，引入4种不同分子结构的双马来酰亚胺(BMI)树脂(BAPP-BMI、DDMBMI、DETDA-BMI、ODA-BMI)，制备了一系列多官能环氧-BMI胶粘剂(JTH-1～JTH-4)，并对各项性能进行检测分析。研究结果表明：固化动力学分析显示，加入2,2-双[4-(4-马来酰亚胺基苯氧基)苯基]丙烷(BAPP-BMI)的JTH-1环氧胶粘剂表观活化能(Ea)为63.74 kJ/mol，固化反应级数(n)为0.9。加入4,4'-双马来酰亚胺二苯醚(ODA-BMI)的JTH-4在粘接方面更有优势，拉伸剪切强度在大部分温度下高于其他3种配方，在-20℃时拉伸剪切强度可达到19.244 MPa。JTH-1较其他3种配方在冲击强度、拉伸强度方面更加优异，分别为14.413 kJ/m2、53.337 MPa。4种配方整体介电稳定性良好，电容波动均≤0.2 pF，具有电容稳定性，且介电性能优异，疏水能力好。本研究为高性能环氧-BMI胶粘剂的分子结构设计与工程化应用提供了试验依据与数据支撑。
In order to improve the toughness,heat resistance,and comprehensive dielectric properties of epoxy resin and broaden its application in electronic packaging,aerospace,and other fields,the multifunctional nitrogen-containing heterocyclic epoxy resin triglycidyl tris(2-hydroxyethyl) isocyanurate(TGTHEIC) was used as the matrix in this study,combined with epoxy resin,carboxyl-terminated liquid nitrile rubber,and 4, 4'-diaminodiphenyl sulfone,and introducing four kinds of bismaleimide(BMI) resin with different molecular structures(BAPP-BMI,DDM-BMI,DETDA-BMI,and ODA-BMI),a series of multifunctional epoxy-BMI adhesive(JTH-1～JTH-4) were prepared,and their properties were tested and analyzed. The research results showed that,curing kinetic analysis revealed that the apparent activation energy(Ea) of JTH-1 epoxy adhesive containing 2, 2-bis[4-(4-maleimidophenoxy)phenyl]propane(BAPP-BMI) was 63.74 kJ/mol,and the curing reaction order(n) was 0.9. JTH-4 containing 4,4'-bismaleimidodiphenyl ether(ODA-BMI) showed advantages in bonding performance,with tensile shear strength exceeding that of other three formulations at most temperatures.At-20 ℃,the tensile shear strength reached 19.244 MPa. JTH-1 was superior to other three formulations in terms of impact strength and tensile strength,with values of 14.413 kJ/m2 and 53.337 MPa,respectively.Four formulations had good overall dielectric stability,with capacitance fluctuations ≤0.2 pF,exhibiting capacitance stability,excellent dielectric performance,and good hydrophobicity.This study provided experimental basis and data support for the molecular structure design and engineering application of high-performance epoxy-BMI adhesive.
高性能环氧结构胶粘剂粘接性能及应用工艺研究
Research on the bonding performance and application process of high-performance epoxy structural adhesive
景君怡;李黎;潘建东;薛刚;袁志刚;薛双乐;孙明明;张斌; Jing Junyi;Li Li;Pan Jiandong;Xue Gang;Yuan Zhigang;Xue Shuangle;Sun Mingming;Zhang Bin;AVIC Chengdu Aircraft Design and Research Institute;针对航空航天结构粘接对室温固化环氧胶粘剂“高强度-高韧性-工艺可靠”的协同需求，本文以自制高性能双组分环氧结构胶为研究对象，系统探究了固化工艺、基材适配性及施工工艺对粘接性能的影响规律。通过DSC、力学测试及楔子试验，分析了25～70℃温度区间内固化度与力学性能的构效关系，并评价了其对铝合金、钛合金及复合材料体系的粘接耐久性与破坏机理。研究结果表明：该胶粘剂在25℃/7 d、50℃/5 h及70℃/3 h三种工艺下均表现出优异的综合性能，室温剪切强度>30 MPa,100℃高温下仍保持>10 MPa，满足航空结构对宽温域性能的要求。该胶粘剂对铝合金、多种钛合金及复合材料均表现出优异的粘接性能，破坏模式多为混合破坏或复合材料层间内聚破坏，证明该胶粘剂对异质材料界面的润湿性与粘接力已达到较高水平。经湿热环境处理后，试样裂纹扩展长度仅为0.1 cm，证实了该胶粘剂具有优异的抗湿热老化能力与长期结构稳定性。针对施工中的气泡缺陷，本研究创新性地提出了基于双组分静态混合与“中心堆胶”相结合的无气泡施胶工艺，并根据被粘件几何特征优化了“工字形”与“米字形”堆胶策略，显著提升了胶层致密性与工艺可控性。本研究为航空结构胶的工程化应用提供了重要的工艺参数与理论支撑。
To address the synergistic demand for “high strength-high toughness-process reliability” of roomtemperature curing epoxy adhesive in aerospace structural bonding,the self-made high-performance two-,component epoxy structural adhesive was employed as the research object in this study the effects of curing process,substrate adaptability,and construction process on adhesion properties were systematically investigated.Through DSC,mechanical testing,and wedge tests,the structure-property relationships between curing degree and mechanical properties in the temperature range of 25-70 ℃ were analyzed,and the bonding durability and failure mechanisms of aluminum alloy,titanium alloys,and composite material systems were evaluated.The research results showed that this adhesive exhibited excellent comprehensive performance under three processes:25 ℃/7 d,50 ℃/5 h,and 70 ℃/3 h.The room temperature shear strength was over 30 MPa,and it still maintained over 10 MPa at 100 ℃,meeting the requirements of aviation structures for wide temperature range performance. This adhesive exhibited excellent adhesion performance to aluminum alloy,various titanium alloys,and composite materials. The failure modes were mostly mixed failure or interlayer cohesive failure of composite materials,proving that the wettability and adhesion strength of this adhesive to heterogeneous material interfaces had reached a high level.After being treated in a humid and hot environment,the crack propagation length of the sample was only 0.1 cm,confirming that the adhesive had excellent resistance to humid and hot aging and had long-term structural stability. To address bubble defects during construction,a bubble-free adhesive application process based on the combination of two-component static mixing and “center pile-up” was innovatively proposed in this study,and “I-shaped” and “asterisk-shaped” pile-up strategies were optimized according to the geometric characteristics of the bonded parts,and significantly improved the density and process controllability of the adhesive layer. This study provided important process parameters and theoretical support for the engineering application of aerospace structural adhesive.
