期刊信息
期刊名称：《中国胶粘剂》CHINA ADHESIVES
创办日期：1986(1973)
主管部门：上海华谊（集团）有限公司
主办单位：上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会
刊 期：月刊
电 话：010-87663098/87663304
Email：GXLJ@chinajournal.net.cn
国内统一刊号(CN)：
CN 31-1601/TQ
国际标准刊号(ISSN)：
ISSN 1004-2849
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本刊介绍
《中国胶粘剂》为重点报道中国胶粘剂科研成果和最新进展的学术期刊，月刊。1973年创刊，原名为《树脂粘合剂》，1979年更名为《粘合剂》，1991年更名为《中国胶粘剂》，2014年12月，成为原国家新闻出版广电总局第一批认定学术期刊。
主管单位是上海华谊控股集团有限公司，主办单位是上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会。
期刊在国内外公开发行，国内发行代号为4-454，国外发行代号为M5121；国内统一连续出版物号为CN31-1601/TQ，国际标准连续出版物号为ISSN 1004-2849。
期刊设有专题综述、研究报告、工艺与应用、材料科学等栏目，主要报道国内外胶粘剂、密封剂和胶粘带行业的最新理论研究成果、原料/设备/制备工艺创新、粘接接头设计制备技术、生产应用实践等论文和综述等，主要涉及领域主要包括化工、轻工、包装、纺织、建筑、机械、电子、航空、航天、汽车、船舶、林木、家具和印刷等领域。
期刊为中国科技核心期刊、RCCSE中国核心学术期刊，《科技期刊世界影响力指数（WJCI）报告》收录期刊，曾为全国中文核心期刊（2007/2011/2014/2017年），现被“中国核心期刊数据库、”“中国期刊全文数据库”、“中国学术期刊综合评价数据库”、《中国学术期刊影响因子年报》统计源、美国《化学文摘》（CA）、中国知网数据库（CNKI）、万方数据库、维普数据库、新华网“学术中国”以及长江文库等收录，先后荣获《CAJ-CD规范》执行优秀期刊、全国石油和化工行业优秀期刊二等奖、全国石油和化工行业优秀期刊一等奖、华东地区优秀期刊奖、上海市科技期刊审读优秀奖、上海市期刊编校质量优秀奖、全国石油和化工学术期刊50强、全国石油和化工行业期刊100强、全国石油和化工学术期刊60强。2024年，期刊还被中国化工学会发布的首版《化工领域高质量科技期刊分级目录》入选为T3级期刊，标志着我刊已进入化工领域“国内外重要、为学术界所认可的期刊”队列。2024年期刊复合影响因子为1.595，综合影响因子为1.309。
《中国胶粘剂》杂志是胶粘剂行业的窗口，是胶粘剂企业的桥梁，是胶粘剂读者的纽带。
胶接技术在惯性制导系统的应用
Application of adhesive bonding technology in inertial guidance system
赵富贵;张军营;程珏; Zhao Fugui;Zhang Junying;Cheng Jue;胶接技术作为惯性制导系统制造与封装的关键工艺，其性能直接决定了系统的精度稳定性与长期可靠性。本文介绍了胶接技术在惯性器件装配、应力隔离与系统级集成保护中的核心作用，以及对不同性能胶接材料和工艺的需求。阐述了现有的不同种类胶粘剂对惯性制导系统的影响以及工艺影响性，剖析了不同胶粘剂在光纤陀螺应用中需要解决的快速固化、低应力、挥发性和低蠕变等四大共性问题。同时提出了不同光纤胶的选胶依据和结构设计思路，并对目前已有光纤胶及相关研究进行阐述。最后，综述了当前主流光纤胶及新型材料的研究进展，并对未来胶接技术在惯性制导领域高性能化发展方向进行了展望，为相关产品的精密制造与设计开发提供参考。
Adhesive bonding technology,as the critical process for the manufacturing and packaging of inertial guidance system,directly determines the precision stability and long term reliability of the system.The core functions of adhesive bonding technology in the assembly of inertial devices,stress isolation and system-level integrated protection,as well as the requirements for adhesive materials and processes with varying performance were introduced in this paper.The impact of existing various types of adhesive on inertial guidance system and their process-induced effect were elaborated,and four common fundamental problems that needed to be addressed when different adhesive was applied to fiber optic gyroscope,namely rapid curing,low stress,volatility and low creep,were analyzed. Meanwhile,the criteria for selecting different fiber optic adhesive and structural design concepts were proposed,and the existing fiber optic adhesive and related research were elaborated. Finally,the research progress of current mainstream fiber optic adhesive and novel materials were summarized,and the future development direction of high performance of adhesive bonding technology in the field of inertial guidance was discussed,providing references for the precision manufacturing,design development of related products.
加成型硅橡胶增黏剂的研究进展
Research progress on addition-type silicone rubber tackifier
王晓晨;柴谦;王国栋;秦佳琦;卢海峰; Wang Xiaochen;Chai Qian;Wang Guodong;Qin Jiaqi;Lu Haifeng;Shandong Center for Medical Device Evaluation and Inspection;Changle People's Hospital of Shandong Second Medical University;加成型硅橡胶因其优异性能得到广泛关注，但其固化后表面能低、化学惰性的特性导致其对基材的粘接性能较差，限制了其应用。加入增黏剂可以有效提升硅橡胶与基材之间的界面作用力，改善粘接强度，解决其粘接难的问题。本文主要简述了近年来加成型硅橡胶增黏剂的设计合成及应用的新进展，系统梳理了多种不同官能团类型的作用机理及改性效果。加成型硅橡胶增黏剂的研究表明，单一官能团增黏剂难以兼顾多基材适配性与环境稳定性。多官能团协同设计、精准界面工程是未来提升增黏剂性能的核心方向，这将为加成型硅橡胶在高端制造、新能源等领域的应用突破提供支撑。
Addition-type silicone rubber has attracted extensive attention due to its excellent properties.However,its low surface energy and chemical inertness after curing result in poor bonding property to substrates,which limits its application.Adding tackifiers can effectively enhance the interfacial interaction between silicone rubber and substrates,improving bonding strength,and addressing the difficulty in bonding.The new progress in the design,synthesis and application of tackifiers for addition-type silicone rubber in recent years was briefly reviewed in this paper,and the action mechanisms and modification effects of various types of functional groups were systematically summarized.Research on addition-type silicone rubber tackifiers has indicated that single functional group tackifiers could hardly balance the adaptability to multiple substrates and environmental stability. The synergistic design of multi-functional groups and precise interfacial engineering would be the core directions for improving the performance of tackifiers in the future,which would provide support for breakthroughs in the application of addition-type silicone rubber in high-end manufacturing,new energy and other fields.
新型BAPP-BMI型耐高温胶粘剂的研制及其固化动力学研究
Development of novel BAPP-BMI high temperature resistant adhesive and its curing kinetics
范天华;虞鑫海; Fan Tianhua;Yu Xinhai;以二烯丙基双酚A(DABPA)与二烯丙基双酚S(DABPS)复配改性2,2-双[4-(4-马来酰亚胺苯氧基)苯基]丙烷(BAPP-BMI)树脂，制备了一种新型耐高温胶粘剂(J01)。采用差示扫描量热法研究了其固化动力学，并对固化物的力学性能、电学性能及吸水性能进行了表征。研究结果表明：耐高温胶粘剂J01的固化工艺为190℃/2 h+220℃/2 h+250℃/2 h+275℃/2 h，表观活化能为102.5 kJ/mol，反应级数为0.917。DABPA/DABPS/BAPP-BMI体系具有良好的力学性能，冲击强度、拉伸强度和弯曲强度分别为37.1 kJ/m2、64.7 MPa和93.4 MPa；胶粘剂的粘接性能良好，室温拉伸剪切强度为15.5 MPa，当温度为300℃时，仍保留4.6 MPa的剪切强度。该体系胶粘剂在宽广的频率范围保持优异的介质稳定性，电容值稳定在4.57～4.65 pF，且具有低介电常数(3.53～3.58)和低介电损耗(0.007 78～0.010 80)，绝缘性好，介电性能优异，测得固化物的平均吸水率为0.38%。综合测试分析表明，该胶粘剂兼具良好的耐热性、力学性能、介电性能与耐湿热稳定性，在高可靠性电子封装领域具有广阔的应用前景。
A novel high temperature resistant adhesive(J01) was prepared by compounding and modifying 2, 2-bis[4-(4-maleimidophenoxy) phenyl] propane(BAPP-BMI) resin with diallylbisphenol A(DABPA) and diallylbisphenol S(DABPS).The curing kinetics were studied by using differential scanning calorimetry,and the mechanical,electrical,and water absorption properties of the cured material were characterized.The research results showed that the curing process of high temperature resistant adhesive J01 was 190 ℃/2 h+220 ℃/2 h+250 ℃/2 h+275 ℃/2 h,with the apparent activation energy of 102.5 kJ/mol and the reaction order of 0.917.The DABPA/DABPS/BAPP-BMI system had excellent mechanical properties,with impact strength,tensile strength,and bending strength of 37.1 kJ/m2,64.7 MPa,and 93.4 MPa,respectively.The adhesive had good bonding performance,with the tensile shear strength of 15.5 MPa at room temperature.When the temperature was 300 ℃,the shear strength of 4.6 MPa was still retained. The adhesive system maintained excellent dielectric stability over a wide frequency range,with the stable capacitance value of 4.57-4.65 pF,low dielectric constant(3.53-3.58) and low dielectric loss(0.007 78-0.010 80).It had good insulation and excellent dielectric properties.The average water absorption rate of the cured product was measured to be 0.38%.Comprehensive testing analysis showed that the adhesive had good heat resistance,mechanical properties,dielectric properties,and moisture and heat stability,demonstrating broad application prospects in the field of high reliability electronic packaging.
短切碳纤维/端羧基液体丁腈橡胶协同改性环氧树脂胶粘剂研究
Study on epoxy resin adhesive synergistically modified by chopped carbon fiber/carboxyl-terminated liquid nitrile rubber
赵明;张雪;孙明明;张绪刚;张斌;袁志刚;李坚辉;王磊; Zhao Ming;Zhang Xue;Sun Mingming;Zhang Xugang;Zhang Bin;Yuan Zhigang;Li Jianhui;Wang Lei;以短切碳纤维、端羧基液体丁腈橡胶（CTBN）、双氰胺以及环氧树脂为主要原料，采用三辊研磨和真空搅拌工艺制备了复合型胶粘剂。对胶粘剂的粘接性能、本体力学性能、耐热性能和微观形貌进行了表征。研究结果表明：CTBN可提升环氧树脂的单搭接拉伸剪切强度，但随胶层厚度增加，剪切强度下降幅度逐渐增大。CTBN与短切碳纤维协同改性后，胶粘剂在0.1～3.0 mm胶层厚度范围内的剪切强度均得到提升，同时本体刚性与玻璃化转变温度有所提高，断裂面呈现韧性断裂形态。当短切碳纤维与CTBN添加量均为20份时，胶粘剂在0.1 mm和1.0 mm胶层厚度下的剪切强度均达到最大值，分别为31.3 MPa和23.6 MPa。短切碳纤维与CTBN复合改性方法可有效提升环氧胶粘剂在不同胶层厚度下的剪切强度，为制备高性能厚胶层粘接用特种胶粘剂提供了参考。
Chopped carbon fiber,carboxyl-terminated liquid nitrile rubber(CTBN),dicyandiamide and epoxy resin were used as main raw materials,composite adhesive was prepared via three-roll grinding and vacuum stirring process. The bonding properties,bulk mechanical properties,heat resistance and micromorphology of adhesive were characterized. The research results showed that CTBN could improve the single-lap tensile shear strength of epoxy resin,but the decreasing amplitude of shear strength gradually increased with the increase of adhesive layer thickness.After synergistic modification by CTBN and chopped carbon fiber,the shear strength of adhesive was improved within the range of 0.1-3.0 mm adhesive layer thickness,meanwhile,its bulk rigidity and glass transition temperature were increased to some extent,and the fracture surface exhibited a ductile fracture morphology.When the addition amounts of chopped carbon fiber and CTBN were both 20 phr,the shear strength of the adhesive all reached maximum value under the adhesive layer thicknesses of 0.1 mm and 1.0 mm,which were 31.3 MPa and 23.6 MPa,respectively.The composite modification method of chopped carbon fiber and CTBN could effectively improve the shear strength of epoxy adhesive at different adhesive layer thicknesses,providing a reference for the preparation of high-performance special adhesive for thick adhesive layer bonding.
高温可剥离聚酰胺酰亚胺胶粘剂的合成及其性能研究
Synthesis and properties of high temperature resistant and peelable polyamide-imide adhesive
刘杰;夏登周;戴安邦;黄剑;李诗丞;万中梁; Liu Jie;Xia Dengzhou;Dai Anbang;Huang Jian;Li Shicheng;Wan Zhongliang;针对高温制程中临时贴合材料在热压阶段需兼具良好的润湿性与高温稳定性、冷却后需实现玻璃化转变温度(Tg)可调控的聚酰胺酰亚胺(PAI)胶粘剂，以2,2-双[4-(4-氨基苯氧基)苯基]丙烷(BAPP)、1,12-二氨基十二烷(DDA)与偏苯三酸酐酰氯(TMAC)为单体，通过调节芳香族/脂肪族二胺比例，合成了3种PAI胶粘剂(PAI-1、PAI-2、PAI-3)，其Tg分别为174、192和222℃。将其涂布于Kapton基膜上固化形成胶层，并与铜箔在200℃热压贴合、冷却后进行剥离测试。研究结果表明：Tg与贴合温度的匹配程度显著影响剥离失效模式与洁净性；Tg接近200℃的PAI-2配方可实现界面主导的稳定脱黏，剥离过程顺畅，铜箔表面无明显残胶与拉丝。扫描电镜观察发现，剥离后胶层表面形成规则褶皱。该形貌与热失配残余应力释放及Tg附近的黏弹松弛/冻结行为密切相关，从微观角度验证了界面主导脱黏的剥离机制。本研究为高温可剥离胶带的配方设计与工艺匹配提供了可操作的调控策略，在高密度封装、柔性电路制造等领域具有潜在应用前景。
In order for polyamide-imide(PAI) adhesive with good wetting properties and high temperature stability during the hot-pressing stage of temporary bonding materials in high temperature process,and controllable glass transition temperature(Tg) after cooling,three types of PAI adhesive(PAI-1,PAI-2 and PAI-3) were synthesized by using 2,2-bis [4-(4-aminophenoxy) phenyl] propane(BAPP),1,12-diaminododecane(DDA),and trimellitic anhydride chloride(TMAC) as monomers and adjusting the ratio of aromatic to aliphatic diamines.Their Tg values were 174,192 and 222 ℃,respectively.They were coated onto Kapton base film and cured to form an adhesive layer. Subsequently,the film was hot-pressed onto copper foil at 200 ℃,and peel strength tests were carried out after cooling.The research results showed that the matching degree between Tg and bonding temperature significantly affected the peel failure mode and cleanliness.The PAI-2 formula with a Tg close to 200 ℃ could achieve stable debonding dominated by the interface,with a smooth peeling process and no obvious residue or wire drawing on the copper foil surface. Scanning electron microscopy observation revealed the formation of uniform wrinkles on the surface of the adhesive layer after peeling.This morphology was closely related to the release of residual stress caused by thermal mismatch as well as the viscoelastic relaxation/freezing behavior near Tg,which verified the interface dominant delamination mechanism from a microscopic perspective. This study provided practical control strategies for the formulation design and process matching of high temperature resistant and peelable adhesive tape,which showed potential application prospects in high-density packaging,flexible circuit manufacturing,and related fields.
基于腰果酚改性的水下环氧胶粘剂的制备与性能研究
Study on the preparation and performance of cardanol-modified underwater epoxy adhesive
卢洪涛;姚静静;靳凯; Lu Hongtao;Yao Jingjing;Jin Kai;Unit 91697 of the Chinese People's Liberation Army;以腰果酚、多聚甲醛和间苯二甲胺为原料，通过曼尼希（Mannich）反应合成了含腰果酚结构的水下固化剂，并与E-51型环氧树脂复合制备了水下环氧胶粘剂。系统研究了合成工艺、固化剂配比、固化时间及3种单体用量对胶粘剂水下粘接性能与力学性能的影响规律。研究结果表明：固化剂的最佳合成工艺为90℃反应4 h；环氧树脂与固化剂的最佳质量比为10∶4，水下固化120 h后性能趋于稳定。当单体物质的量之比n（腰果酚）∶n（多聚甲醛）∶n（间苯二甲胺）=1∶1∶1.4时，胶粘剂的综合性能最优，水下粘接强度达9.52 MPa，同时具有良好的拉伸强度（35 MPa）和压缩强度（80.24 MPa）。研究证实，腰果酚的引入可有效提升胶粘剂的韧性、耐水性及固化促进效果，但过量使用会降低材料刚性，导致拉伸与压缩强度下降。该研究为开发兼具良好水下粘接性能与力学平衡性的环氧胶粘剂提供了理论与试验依据。
An underwater curing agent containing cardanol structure was synthesized by using cardanol,paraformaldehyde and m-xylylenediamine as raw materials via Mannich reaction,and then an underwater epoxy adhesive was prepared by compounding it with E-51 epoxy resin.The influence of synthesis process,curing agent ratio,curing time as well as the dosage of three monomers on the underwater bonding performance and mechanical properties of the adhesive were systematically investigated.The research results showed that the optimal synthesis process of the curing agent was reaction at 90 ℃ for 4 h.The optimal mass ratio of epoxy resin to curing agent was 10∶4,and the performance tended to be stable after underwater curing for 120 h.When the monomer molar ratio n(cardanol)∶n(paraformaldehyde)∶n(m-xylylenediamine)=1∶1∶1.4,the adhesive exhibited the optimal comprehensive performance,with an underwater bonding strength of 9.52 MPa,as well as favorable tensile strength(35 MPa) and compressive strength(80.24 MPa).The study confirmed that the introduction of cardanol effectively improved the toughness,water resistance and curing acceleration effect of the adhesive,but excessive addition could reduce the rigidity of the material and lead to decreases in tensile and compressive strength. This study provided theoretical and experimental foundations for developing epoxy adhesive with both favorable underwater bonding performance and balanced mechanical properties.
