期刊信息
期刊名称：《中国胶粘剂》CHINA ADHESIVES
创办日期：1986(1973)
主管部门：上海华谊（集团）有限公司
主办单位：上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会
刊 期：月刊
电 话：010-87663098/87663304
Email：GXLJ@chinajournal.net.cn
国内统一刊号(CN)：
CN 31-1601/TQ
国际标准刊号(ISSN)：
ISSN 1004-2849
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本刊介绍
《中国胶粘剂》为重点报道中国胶粘剂科研成果和最新进展的学术期刊，月刊。1973年创刊，原名为《树脂粘合剂》，1979年更名为《粘合剂》，1991年更名为《中国胶粘剂》，2014年12月，成为原国家新闻出版广电总局第一批认定学术期刊。
主管单位是上海华谊控股集团有限公司，主办单位是上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会。
期刊在国内外公开发行，国内发行代号为4-454，国外发行代号为M5121；国内统一连续出版物号为CN31-1601/TQ，国际标准连续出版物号为ISSN 1004-2849。
期刊设有专题综述、研究报告、工艺与应用、材料科学等栏目，主要报道国内外胶粘剂、密封剂和胶粘带行业的最新理论研究成果、原料/设备/制备工艺创新、粘接接头设计制备技术、生产应用实践等论文和综述等，主要涉及领域主要包括化工、轻工、包装、纺织、建筑、机械、电子、航空、航天、汽车、船舶、林木、家具和印刷等领域。
期刊为中国科技核心期刊、RCCSE中国核心学术期刊，《科技期刊世界影响力指数（WJCI）报告》收录期刊，曾为全国中文核心期刊（2007/2011/2014/2017年），现被“中国核心期刊数据库、”“中国期刊全文数据库”、“中国学术期刊综合评价数据库”、《中国学术期刊影响因子年报》统计源、美国《化学文摘》（CA）、中国知网数据库（CNKI）、万方数据库、维普数据库、新华网“学术中国”以及长江文库等收录，先后荣获《CAJ-CD规范》执行优秀期刊、全国石油和化工行业优秀期刊二等奖、全国石油和化工行业优秀期刊一等奖、华东地区优秀期刊奖、上海市科技期刊审读优秀奖、上海市期刊编校质量优秀奖、全国石油和化工学术期刊50强、全国石油和化工行业期刊100强、全国石油和化工学术期刊60强。2024年，期刊还被中国化工学会发布的首版《化工领域高质量科技期刊分级目录》入选为T3级期刊，标志着我刊已进入化工领域“国内外重要、为学术界所认可的期刊”队列。2024年期刊复合影响因子为1.595，综合影响因子为1.309。
《中国胶粘剂》杂志是胶粘剂行业的窗口，是胶粘剂企业的桥梁，是胶粘剂读者的纽带。
国内外无色透明环氧胶粘剂研究进展
Research progress of colorless and transparent epoxy adhesive at home and abroad
朱宸廷;虞鑫海; Zhu Chenting;Yu Xinhai;无色透明环氧胶粘剂因其独特的透明性和优异的机械性能，在众多领域具有广泛的应用前景。随着科技的发展和市场需求的不断增长，无色透明环氧胶粘剂在航空航天、汽车工业、电子电气以及光学仪器等领域得到了越来越多的关注。本文综述了无色透明环氧胶粘剂的研究进展、种类、制备方法、性能指标及其在不同工业领域的应用情况。在无色透明环氧树脂的研究与应用方面，双酚A型、双酚F型、氢化双酚A型环氧树脂及其他新型无色透明环氧树脂均表现出了独特的性能。通过添加各种改性剂、填料或选择不同的固化剂，可以显著提升环氧树脂的机械性能、耐热性、透明度等关键性能指标。随后对其市场现状和应用领域进行介绍，最后对未来发展进行了展望。
Colorless and transparent epoxy adhesive has broad application prospects in many fields due to its unique transparency and excellent mechanical properties.With the development of technology and the continuous growth of market demand,colorless and transparent epoxy adhesive has received increasing attention in fields such as aerospace,automotive industry,electronic and electrical,and optical instruments.The research progress,types,preparation methods,performance indicators,and application in different industrial fields of colorless and transparent epoxy adhesive were reviewed in this paper.In terms of the research and application of colorless and transparent epoxy resin,bisphenol A type,bisphenol F type,hydrogenated bisphenol A type epoxy resins,and other new colorless and transparent epoxy resins all exhibited unique properties.By adding various modifiers,fillers,or selecting different curing agents,the mechanical properties,heat resistance,transparency,and other key performance indicators of epoxy resin could be significantly improved. Subsequently,the market status and application areas were introduced,and finally,the future development prospects were discussed.
骨胶的研究及应用现状
Research and application of bone glue
杨玉娜;侯清娥;高红芳;薛萍;蒋宝;许海媛; Yang Yuna;Hou Qinge;Gao Hongfang;Xue Ping;Jiang Bao;Xu Haiyuan;Weinan Vocational and Technical College;骨胶是一种在木材、包装、农业等行业得到广泛应用、具有广阔推广市场的天然高分子胶粘剂，其生产原料来源广泛，成本较低，环保无污染。本文概述了骨胶的改性方法、应用领域等方面的研究和现状，指出了骨胶作为胶粘剂当前存在的优势和不足，希望能为骨胶的相关研究提供参考，进而扩展骨胶的应用范围。
Bone glue is a natural polymer adhesive widely used in industries such as wood,packaging,and agriculture,with a broad market for promotion. Its production raw materials are widely sourced,the cost is low,and it is environmentally friendly and pollution-free. The research and current status of modification methods and application fields of bone glue were summarized in this article,and the advantages and disadvantages of bone glue as adhesive were pointed out. It was hoped that this could provide reference for related research on bone glue and expand its application scope.
软段结构对于水性聚氨酯性能的影响
The influence of soft segment structure on the performance of waterborne polyurethane
徐一平;张嘉琦;翟瑞雪;周超; Xu Yiping;Zhang Jiaqi;Zhai Ruixue;Zhou Chao;以异佛尔酮二异氰酸酯（IPDI）为硬段，2,2-双（羟甲基）丙酸（DMPA）、1,4-丁二醇（BDO）为主要原料，分别以聚碳酸酯二醇（PCDL）、聚己内酯二醇（PCL）、聚己二酸-1,4-丁二醇酯二醇（PBA）、聚四氢呋喃二醇（PTMG）和聚丙二醇（PPG）为多元醇，通过预聚体法和丙酮法相结合的方法制备了5种不同软段结构（PCDL、PCL、PBA、PTMG和PPG）的水性聚氨酯（WPU）。揭示了软段结构对材料热性能、力学性能、黏附性能以及耐水性的影响。研究结果表明：PCDL基WPU在热性能、力学性能和耐水性能方面表现优异，但过高的刚性可能限制其在某些柔性应用中的使用；PCL和PBA基WPU在综合性能上表现均衡，适合对热稳定性和力学性能有一定要求的应用场景；而PPG基WPU因其高柔顺性和低玻璃化转变温度，适用于对柔韧性要求较高的领域，但其热稳定性和耐水性能需进一步优化。
Using isophorone diisocyanate(IPDI) as the hard segment,2, 2-bis(hydroxymethyl) propionic acid(DMPA),and 1,4-butanediol(BDO) as the main raw materials,five different soft segment structures(PCDL,PCL,PBA,PTMG,and PPG) of waterborne polyurethane(WPU) were prepared by combining pre-polymerization and acetone methods,with polycarbonate diol(PCDL),polycaprolactone diol(PCL),poly(1,4-butanediol adipate) diol(PBA),poly(tetrahydrofuran) diol(PTMG),and polypropylene glycol(PPG) as polyols.The influence of soft segment structure on the thermal properties,mechanical properties,bonding performance,and water resistance of the materials was revealed. The research results showed that PCDL based WPU exhibited excellent thermal,mechanical,and water resistance properties,but its excessively high rigidity might limit its use in certain flexible applications. PCL and PBA based WPU exhibited balanced overall performance,making them suitable for application scenarios with certain requirements for thermal stability and mechanical properties.PPG based WPU was suitable for fields that required high flexibility due to its high flexibility and low glass transition temperature,but its thermal stability and water resistance needed to be further optimized.
氮化硼对丙烯酸酯导热结构胶的改性研究
Study on the modification of boron nitride to acrylate thermal conductive structural adhesive
刘妹;葛冰洁;戚安杰;于竹青;项尚林; Liu Mei;Ge Bingjie;Qi Anjie;Yu Zhuqing;Xiang Shanglin;为解决氮化硼纳米颗粒与高分子基材难以浸润相容、分散性差、易团聚的难题，本文以改性氮化硼（BN）、环氧丙烯酸酯齐聚物、甲基丙烯酸月桂酯（LMA）、三官能团酸酯（SR9051 NS）、偶氮二异丁腈（AIBN）和对苯二酚等为原料，制备了丙烯酸酯导热结构胶，并对其流变性能、导热性能、粘接性能等进行表征。研究结果表明：导热结构胶的黏度及其固化物的导热系数随改性氮化硼用量的增加而增大，改性氮化硼用量为40%时，导热结构胶的导热系数相比未添加氮化硼的结构胶提升了540%。随着改性氮化硼含量的增加，剪切强度呈现先增加后下降的趋势，其中20%BN/SA导热结构胶的剪切强度最高可达15 MPa。
To solve the problems of difficult infiltration compatibility,poor dispersibility,and easy aggregation between boron nitride nanoparticles and polymer substrates,acrylic thermal conductive structural adhesive was prepared in this paper by using modified boron nitride(BN),epoxy acrylate oligomers,lauryl methacrylate(LMA),trifunctional acid ester(SR9051 NS),azobisisobutyronitrile(AIBN),and hydroquinone as raw materials,and its rheological properties,thermal conductivity,and bonding properties were characterized. The research results showed that the viscosity of thermal conductive structural adhesive and the thermal conductivity of its cured material increased with the increase of modified boron nitride amount.When the amount of modified boron nitride was 40%,the thermal conductivity of thermal conductive structural adhesive was 540% higher than that of the structural adhesive without boron nitride added.With the increase of modified boron nitride amount,the shear strength showed a trend of first increasing and then decreasing,among which the shear strength of 20%BN/SA thermal conductive structural adhesive could reach up to 15 MPa.
硫酸钙晶须对环氧树脂胶粘剂粘接强度及热性能的影响
Effect of calcium sulfate whiskers on bonding strength and thermal properties of epoxy resin adhesive
赵明;张雪;孙明明;张绪刚;张斌;李坚辉;王磊;李金籽; Zhao Ming;Zhang Xue;Sun Mingming;Zhang Xugang;Zhang Bin;Li Jianhui;Wang Lei;Li Jinzi;按照70∶30∶20的质量比例将WSR618型环氧树脂、AG-80型环氧树脂、增韧剂进行混合，组成主体树脂体系，以双氰胺、有机脲为固化促进剂体系，并添加硅烷偶联剂、硫酸钙晶须填料组成胶粘剂体系。考察了硫酸钙晶须填料对环氧树脂胶粘剂在不同胶层厚度下单搭接剪切强度的影响，并对添加硫酸钙晶须的胶粘剂体系的固化反应热、玻璃化转变温度(Tg)、膨胀系数、热稳定性进行了研究。研究结果表明：(1)在环氧树脂胶粘剂中添加硫酸钙晶须可以降低胶粘剂随胶层增厚而单搭接剪切强度下降的幅度，并在一定程度上增强了胶粘剂在0.5 mm和1.0 mm厚胶层下的剪切强度。(2)添加硫酸钙晶须能降低环氧树脂胶粘剂体系的固化反应热，提高体系固化反应峰值温度。(3)硫酸钙晶须的加入降低了胶粘剂体系的Tg，当其添加量为10份时体系Tg的降低幅度很小，当添加量超过10份时，体系Tg的降低幅度开始变大。(4)添加硫酸钙晶须能降低环氧树脂胶粘剂体系的热膨胀系数(
WSR618 epoxy resin,AG-80 epoxy resin,and toughening agent were mixed in a mass ratio of 70∶30∶20 to form the main resin system.Dicyandiamide and organic urea were used as curing accelerators,and silane coupling agent and calcium sulfate whiskers filler were added to form the adhesive system.The effect of calcium sulfate whisker filler on the single lap shear strength of epoxy resin adhesive at different adhesive layer thicknesses was investigated,and the curing reaction heat,glass transition temperature(Tg),expansion coefficient,and thermal stability of the adhesive system with calcium sulfate whiskers added were studied.The research results showed that,(1) Adding calcium sulfate whiskers to epoxy resin adhesive could reduce the magnitude of the decrease in single lap shear strength of the adhesive as the adhesive layer thickened,and to some extent enhanced the shear strength of the adhesive under 0.5 mm and 1.0 mm thick adhesive layers.(2) Adding calcium sulfate whiskers could reduce the curing reaction heat of epoxy resin adhesive system and increased the peak curing reaction temperature of the system.(3) The addition of calcium sulfate whiskers reduced the Tg of the adhesive system. When the addition amount was 10 phr,the decrease in Tg of the system was very small.When the addition amount exceeded 10 phr,the decrease in Tg of the system began to increase.(4) Adding calcium sulfate whiskers could reduce the thermal expansion coefficient(
具有全温域特性聚氨酯结构胶的制备与性能研究
Preparation and performance study of polyurethane structural adhesive with full temperature range characteristics
龚鸿亮; Gong Hongliang;采用多元醇组分（包括小分子扩链剂1,4-丁二醇、分子量为5 000的三官能度大分子聚醚）、异氰酸酯组分（包括特制的聚氨酯预聚体、碳化二亚胺改性液化MDI、粗MDI等）和其他助剂（填料、分子筛活化粉、消泡剂等），制备了一种双组分聚氨酯结构胶粘剂。测试了其在较宽温度范围内各项性能（拉伸强度、断裂伸长率、剪切强度、储能模量）以及热性能分析。另外，还研究了不同扩链剂或交联剂对全温域体系性能的影响。研究结果表明：（1）QWY-1制备的聚氨酯结构胶表现出很好的低温韧性和全温域特性。在低温下（-30℃）有很高的本体强度，达到29.67 MPa，同时表现为很高的断裂韧性，断裂伸长率高达330%左右。另外，其在-40～80℃范围内各项力学性能稳定，不随着温度有较大的变化幅度，可以规避掉由于玻璃化转变温度引起的材料性能的突变。（2）通过不同的扩链剂或交联剂可以制备出不同模量梯度的全温域特性聚氨酯结构胶（QWY-1、QWY-2和QWY-3胶样），其25℃模量分别为57.52、15.97和663.77 MPa。其中，QWY-3胶样表现为出色的低温韧性和高温强度，其60℃下的拉伸强度达12.23 MPa，断裂伸长率为39.07%，也表现出一定的全温域特性。
Two-component polyurethane structural adhesive was prepared by using polyol components(including small molecule chain extender 1,4-butanediol,trifunctional macromolecule polyether with a molecular weight of 5 000),isocyanate components(including specially formulated polyurethane prepolymers,carbodiimide modified liquefied MDI,crude MDI,etc.),and other additives(fillers,molecular sieve activation powder,defoamers,etc.).Its various properties(tensile strength,elongation at break,shear strength,storage modulus) and thermal performance analysis over a wide temperature range were tested.In addition,the influence of different chain extenders or crosslinkers on the performance of the full temperature range system was also studied.The research results showed that,(1) The polyurethane structural adhesive prepared by QWY-1 exhibited excellent lowtemperature toughness and full temperature range characteristics.At low temperatures（-30 ℃）,it had high intrinsic strength,reaching 29.67 MPa,and exhibited high fracture toughness,with elongation at break of about 330%.In addition,its mechanical properties were stable within the range of-40～80 ℃,without significant changes with temperature,which could avoid sudden changes in material properties caused by glass transition temperature.(2) By using different chain extenders or crosslinkers,polyurethane structural adhesive with different modulus gradients could be prepared in the full temperature range(QWY-1,QWY-2,and QWY-3 samples),with modulus of 57.52,15.97,and 663.77 MPa at 25 ℃,respectively.Among them,QWY-3 adhesive sample exhibited excellent low-temperature toughness and high-temperature strength,with tensile strength of 12.23 MPa at 60 ℃ and elongation at break of 39.07%,demonstrating certain full temperature range characteristics.
