期刊信息
期刊名称：《中国胶粘剂》CHINA ADHESIVES
创办日期：1986(1973)
主管部门：上海华谊（集团）有限公司
主办单位：上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会
刊 期：月刊
电 话：010-87663098/87663304
Email：GXLJ@chinajournal.net.cn
国内统一刊号(CN)：
CN 31-1601/TQ
国际标准刊号(ISSN)：
ISSN 1004-2849
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本刊介绍
《中国胶粘剂》为重点报道中国胶粘剂科研成果和最新进展的学术期刊，月刊。1973年创刊，原名为《树脂粘合剂》，1979年更名为《粘合剂》，1991年更名为《中国胶粘剂》，2014年12月，成为原国家新闻出版广电总局第一批认定学术期刊。
主管单位是上海华谊控股集团有限公司，主办单位是上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会。
期刊在国内外公开发行，国内发行代号为4-454，国外发行代号为M5121；国内统一连续出版物号为CN31-1601/TQ，国际标准连续出版物号为ISSN 1004-2849。
期刊设有专题综述、研究报告、工艺与应用、材料科学等栏目，主要报道国内外胶粘剂、密封剂和胶粘带行业的最新理论研究成果、原料/设备/制备工艺创新、粘接接头设计制备技术、生产应用实践等论文和综述等，主要涉及领域主要包括化工、轻工、包装、纺织、建筑、机械、电子、航空、航天、汽车、船舶、林木、家具和印刷等领域。
期刊为中国科技核心期刊、RCCSE中国核心学术期刊，《科技期刊世界影响力指数（WJCI）报告》收录期刊，曾为全国中文核心期刊（2007/2011/2014/2017年），现被“中国核心期刊数据库、”“中国期刊全文数据库”、“中国学术期刊综合评价数据库”、《中国学术期刊影响因子年报》统计源、美国《化学文摘》（CA）、中国知网数据库（CNKI）、万方数据库、维普数据库、新华网“学术中国”以及长江文库等收录，先后荣获《CAJ-CD规范》执行优秀期刊、全国石油和化工行业优秀期刊二等奖、全国石油和化工行业优秀期刊一等奖、华东地区优秀期刊奖、上海市科技期刊审读优秀奖、上海市期刊编校质量优秀奖、全国石油和化工学术期刊50强、全国石油和化工行业期刊100强、全国石油和化工学术期刊60强。2024年，期刊还被中国化工学会发布的首版《化工领域高质量科技期刊分级目录》入选为T3级期刊，标志着我刊已进入化工领域“国内外重要、为学术界所认可的期刊”队列。2024年期刊复合影响因子为1.595，综合影响因子为1.309。
《中国胶粘剂》杂志是胶粘剂行业的窗口，是胶粘剂企业的桥梁，是胶粘剂读者的纽带。
胶粘剂在微型扬声器中的应用及发展
Application and development of adhesive in micro speaker
程真真;王海荣;谈彩花;张增辉;王梦媚;刘春利;周厚强;李春; Cheng Zhenzhen;Wang Hairong;Tan Caihua;Zhang Zenghui;Wang Mengmei;Liu Chunli;Zhou Houqiang;Li Chun;微型扬声器在电子产品中，特别是在日常应用中非常广泛，比如手机、手表、耳机和VR等。微型扬声器最重要的组装方式之一就是粘接，胶粘剂的作用举足轻重。本文综述性地介绍了微型扬声器常用的胶粘剂，比如紫外线固化胶、瞬干胶、改性硅胶、厌氧胶以及反应型热熔胶等，以及常见的粘接应用，包括球顶和振膜的粘接、球顶和音圈的粘接、振膜和边框的粘接、磁铁和盆架的粘接、盆架和边框的粘接、单体与模组的粘接以及上下壳粘接等，并对微型扬声器用胶粘剂的发展趋势进行了展望。
Micro speaker is widely used in electronic products,especially in daily applications such as mobile phones,watches,headphones,and VR.One of the most important assembly methods for micro speaker is bonding,and the role of adhesive is crucial.A comprehensive overview of commonly used adhesive for micro speaker was provided in this article,such as UV cured adhesive,instant adhesive,modified silicone adhesive,anaerobic adhesive,and reactive hot melt adhesive,as well as common bonding applications,including bonding between the dome and diaphragm,the dome and voice coil,the diaphragm and frame,the magnet and basin holder,the basin holder and frame,the individual unit and module,and the upper and lower shells. The development trend of adhesive for micro speaker was also discussed.
虫胶片类型与粘接基底表面状态对粘接强度及其波动性的影响研究
Research on the influence of shellac flake type and surface state of bonding substrate on bonding strength and its fluctuation
谢钰洁;潘晓磊;吴冶平;李高明;古云松;赵秀丽;张平;张银宇; Xie Yujie;Pan Xiaolei;Wu Yeping;Li Gaoming;Gu Yunsong;Zhao Xiuli;Zhang Ping;Zhang Yinyu;虫胶片作为一种天然胶粘剂，因其施工便捷、力学性能较好而受到广泛关注。然而，虫胶原胶的性能易受气候、品种的影响，且目前缺乏针对塑料和金属基底的粘接工艺研究，导致其粘接强度波动性较大，进而影响粘接连接的可靠性。本文通过改变虫胶片类型、虫胶-乙醇溶液(虫胶漆)配制有效期、晾置时间以及粘接基底的种类等变量，发现虫胶片的粘接强度与其理化性质密切相关。酸值达标且溶液黏度较高的虫胶片表现出更优的粘接性能，同时具有较高的熔点(Tm)和熔化热焓(ΔHm)、较低熔程(ΔTm)的虫胶片通常具有更高的粘接强度。粘接工艺方面，基底表面均匀涂覆单层虫胶漆，并于涂胶后立即完成叠合，可获得最佳粘接性能。此外，粘接材质对虫胶片的固化过程和粘接性能存在显著影响，其中聚甲基丙烯酸甲酯(PMMA)的粘接强度最高(约2.8 MPa)，铝片次之(约1.0 MPa)，聚醚醚酮(PEEK)最低(约0.5 MPa)。基底经过打磨处理虽能提升粘接强度，但需延长固化时间以达到最佳性能。本文为优化虫胶片粘接工艺和提高其在不同基底上的粘接性能提供了理论依据和实践指导。
Shellac flakes,as natural adhesive,have received significant attention due to their ease of application and favorable mechanical properties. However,the performance of raw shellac is easily affected by climate and variety,and there is currently a lack of research on bonding processes for plastic and metal substrates,resulting in significant fluctuations in bonding strength and affecting the reliability of bonding connections.It was found in this article that the bonding strength of shellac flakes was closely related to their physical and chemical properties by changing variables such as the type of shellac flakes,the effective period of shellac-ethanol solution(shellac paint) preparation,the drying time,and the type of bonding substrate.Shellac flakes that met the acid value standard and had higher solution viscosity exhibited better bonding performance,while shellac flakes with higher melting points(Tm) and melting enthalpy(ΔHm),as well as lower melting ranges(ΔTm) typically had higher bonding strength.In terms of bonding process,the substrate surface was uniformly coated with a single layer of shellac paint,and the lamination was completed immediately after bonding to achieve the best bonding performance.In addition,the bonding material had a significant impact on the curing process and bonding performance of shellac flakes,with polymethyl methacrylate(PMMA) having the highest bonding strength(about 2.8 MPa),followed by aluminum sheet(about 1.0 MPa),and polyether ether ketone(PEEK) having the lowest(about 0.5 MPa).Although polishing the substrate could improve the bonding strength,it was necessary to extend the curing time to achieve optimal performance.This article provided theoretical basis and practical guidance for optimizing the bonding process of shellac flakes and improving their bonding performance on different substrates.
汽车内饰用乳液型丙烯酸酯压敏胶的研制
Development of emulsion-type acrylate pressure sensitive adhesive for automotive interior trim
李铭杰;李健雄; Li Mingjie;Li Jianxiong;采用丙烯酸丁酯（BA）、丙烯酸异辛酯（2-EHA）、丙烯酸（AA）、马来酸二丁酯（DBM）和甲基丙烯酸甲酯（MMA）为单体，烯丙基醚磺酸盐为乳化剂，过硫酸钾（KPS）-亚硫酸氢钠氧化还原体系为引发剂，碳酸氢钠为pH调节剂，同时添加复合型润湿剂、缔合型增稠剂、中和剂和松香树脂增黏乳液等，制备了一款高剥离力、抗反弹、低气味和低挥发性有机物（VOC）汽车内饰用乳液型丙烯酸酯压敏胶。采用单因素试验法探讨了反应型乳化剂的用量、引发剂的用量、功能单体的用量、DBM单体的用量和水性松香增黏乳液的用量对乳液型压敏胶180°剥离力和应用性能的影响。研究结果表明：乳化剂用量为单体总质量的2.0%，引发剂用量为单体总质量的0.7%，功能单体用量为单体总质量的2.5%,DBM用量为单体总质量的2.0%，水性松香增黏乳液加入量为丙烯酸酯乳液质量的10%，乳液型压敏胶的性能相对最优。反应型乳化剂的用量影响乳液聚合过程以及丙烯酸酯聚合物的分子量和分布，功能单体的用量影响压敏胶的180°剥离力和乳液聚合的稳定性，适量的DBM单体可以提升乳液型压敏胶的初粘力和抗反弹性能，水性松香增黏乳液可以显著提升乳液型压敏胶的180°剥离力但影响抗反弹性能。制备的胶带产品气味在2.5～3.5级之间，抗反弹性能为A+，乳液型压敏胶满足汽车内饰要求的低气味、低VOC、低释放性气味物质（FOG）的行业标准及应用性能要求。
Using butyl acrylate(BA),2-ethylhexyl acrylate(2-EHA),acrylic acid(AA),dibutyl maleate(DBM),and methyl methacrylate(MMA) as monomers,allyl ether sulfonate as emulsifier,potassium persulfate(KPS)-sodium bisulfite redox system as initiator,and sodium bicarbonate as pH regulator,and adding composite wetting agent,associative thickener,neutralizer and rosin resin tackifying emulsion,a kind of emulsion-type acrylate pressure sensitive adhesive with high peel strength,anti-rebound,low odor and low volatile organic compound(VOC) for automotive interior trim was prepared. The effects of the amount of reactive emulsifier,initiator,functional monomer,DBM monomer and waterborne rosin tackifying emulsion on the 180° peel strength and application performance of emulsion-type pressure sensitive adhesive were investigated by single factor test.The research results showed that,the amount of emulsifier was 2.0% of the total mass of monomer,the amount of initiator was 0.7% of the total mass of monomer,the amount of functional monomer was 2.5% of the total mass of monomer,the amount of DBM was 2.0% of the total mass of monomer,the amount of water-borne rosin tackifying emulsion was 10% of the mass of acrylate emulsion,the performance of emulsion-type pressure sensitive adhesive was relatively optimal.The amount of reactive emulsifier affected the emulsion polymerization process as well as the molecular weight and distribution of acrylate polymer.The amount of functional monomer affected the 180° peel force of pressure sensitive adhesive and the stability of emulsion polymerization.An appropriate amount of DBM monomer could improve the initial tack and anti rebound performance of emulsion-type pressure sensitive adhesive.The waterborne rosin tackifying emulsion could significantly improve the 180° peel force of emulsion-type pressure sensitive adhesive,but affected the anti rebound performance.The smell of the prepared tape product was between 2.5 and 3.5 levels,and the anti rebound performance was A+.The emulsion-type pressure sensitive adhesive met the industry standard and application performance requirements of low odor,low VOC,and low release odor substance(FOG) required for automotive interior trim.
CTBN/PPE改性环氧胶粘剂的制备及力学性能研究
Preparation and mechanical properties of epoxy adhesive modified by CTBN/PPE
侯燕;王金朝;杨扬;陈涛;林新志;张红元;曾飞; Hou Yan;Wang Jinzhao;Yang Yang;Chen Tao;Lin Xinzhi;Zhang Hongyuan;Zeng Fei;针对乙烯-醋酸乙烯共聚物(EVA)泡沫板大厚度和耐海洋环境使用的需求，对环氧胶粘剂进行改性。本文采用端羧基丁腈橡胶(CTBN)和端羟基聚苯醚(PPE)对环氧树脂(EP)进行增韧改性，聚酰胺和聚醚胺为固化剂，研究了CTBN/PPE不同添加量对改性环氧胶粘剂的力学性能和粘接性能的影响，并对其力学性能和凝胶时间进行测定。研究结果表明：CTBN/PPE改性环氧胶粘剂能够明显促进EP的固化。当CTBN/PPE的质量添加量为15%时，改性EP体系的弯曲强度达到最大值62.5 MPa，冲击强度达到最大值19.1 kJ/m2，比未改性的EP体系分别提高了66.4%和65.3%。改性环氧胶粘剂对EVA-EVA板材进行粘接时，均表现出较好的剥离强度和拉剪强度，经过70℃人工海水浸泡后仍保持较好的剥离强度；对玻纤-玻纤复合板进行粘接，当CTBN/PPE添加量为15%时，拉剪强度达到了最大值17.2 MPa，比未改性EP的拉剪强度提高了81.2%。
The epoxy adhesive was modified to meet the requirements of ethylene-vinyl acetate copolymer(EVA) foam board for large thickness and marine environment resistance.In this paper,carboxyl terminated nitrile rubber(CTBN) and hydroxyl terminated polyphenylene ether(PPE) were used to toughen epoxy resin(EP).Polyamide and polyether amine were used as curing agents.The effects of different addition amounts of CTBN/PPE on the mechanical properties and bonding properties of modified epoxy adhesive were studied,and its mechanical properties and gel time were measured.The research results showed that CTBN/PPE modified epoxy adhesive could significantly promote the curing of EP. When the mass addition of CTBN/PPE was 15%,the flexural strength of modified EP system reached its maximum value of 62.5 MPa,and the impact strength reached its maximum value of 19.1 kJ/m2,which was 66.4% and 65.3% higher than the unmodified EP system,respectively.When modified epoxy adhesive was used to bond EVA-EVA boards,it exhibited good peel strength and tensile shear strength,and maintained good peel strength even after immersion in artificial seawater at 70 ℃.When bonding the fiberglassfiberglass composite panels,the tensile shear strength reached its maximum value of 17.2 MPa when the CTBN/PPE addition amount was 15%,which was 81.2% higher than the tensile shear strength of unmodified EP.
油箱防护胶低温固化性影响因素的研究
Study on influencing factors of low temperature curing of fuel tank protective adhesive
秦丽;任飞;李守锋;骆志超; Qin Li;Ren Fei;Li Shoufeng;Luo Zhichao;油箱防护胶用于汽车油箱表面的防护，起到防腐、减震、降噪的作用。为满足汽车主机厂降低烘烤温度、缩短烘烤时间的要求，本研究通过对油箱防护胶的低温固化性影响因素及有效调整方法进行研究。采用增塑剂（DINP、Mesamoll）复配使用，PVC掺混树脂和氯醋树脂协同作用，制备了油箱防护胶，并进行了涂膜附着性、力学性能及操作性的研究，以期达到低温固化性的要求。研究结果表明：（1）PVC树脂低温塑化性筛选中，氯醋树脂表现最优，其次是PVC糊树脂，最后为PVC掺混树脂。当w（氯醋树脂）=15%时，最终选择w(PVC掺混树脂)=3%，喷涂施工性、涂膜性能相对最优。（2）通过对增塑剂种类和配比的研究，最终选用DINP作为增塑剂、Mesamoll为辅助增塑剂联合使用。初步确定增塑剂复配使用占比30%，其中Mesamoll配比3%～7%。（3）聚酰胺增黏剂在低温固化性方面贡献不明显，当增黏剂配比为1.3%时可以达到很好的附着作用。（4）从经济利益、产品性能综合考虑，选择增塑剂w(Mesamoll)=3%,w(DINP)=27%为最佳配比。
Fuel tank protective adhesive is used to protect the surface of car fuel tanks,playing a role in corrosion prevention,shock absorption,and noise reduction. In order to meet the requirements of automobile manufacturers to reduce baking temperature and shorten baking time,the factors affecting the low temperature curing of fuel tank protective adhesive and effective adjustment methods were investigated in this study.A fuel tank protective adhesive was prepared by compounding plasticizers(DINP,Mesamoll) and synergistically mixing PVC blended resin with vinyl chloride-acetate copolymer.The adhesion,mechanical properties,and operability of the coating film were studied to meet the requirements of low temperature curing.The research results showed that,(1) In the low temperature plasticization screening of PVC resin,vinyl chloride-acetate copolymer performed the best,followed by PVC paste resin,and finally PVC blended resin.When w(vinyl chloride-acetate copolymer)=15%,the final choice of w(PVC blended resin)=3% resulted in relatively optimal spraying application and coating performance.(2) After studying the types and ratios of plasticizers,DINP was ultimately selected as the plasticizer and Mesamoll was used in combination as the auxiliary plasticizer.It has been preliminarily determined that the proportion of plasticizer compound used was 30%,with Mesamoll ratio ranging from 3% to 7%.(3) The contribution of polyamide tackifier in low temperature curing was not significant,but good adhesion could be achieved when the proportion of tackifier was 1.3%.(4) Considering both economic benefits and product performance,the optimal ratio for plasticizer w(Mesamoll) was 3% and w(DINP) was 27%.
高芯片剪切强度的单组分环氧导电银胶的制备及性能研究
Preparation and performance study of one-component epoxy conductive silver adhesive with high chip shear strength
杨晓杨;林泽锋;伦英慧;王冬雪;王通;周迎春; Yang Xiaoyang;Lin Zefeng;Lun Yinghui;Wang Dongxue;Wang Tong;Zhou Yingchun;本文研究并分析了银粉种类、固化剂种类和添加量以及促进剂种类等重要因素对导电银胶电学和力学性能的影响，评估并分析了导电银胶粘接不同界面的力学性能。最终确定以银粉负载量为80%，双氰胺类固化剂在树脂中添加量为8.3%，促进剂选用复合促进剂，制备了具有较长的室温适用期的单组分导电银胶。研究结果表明：导电银胶具有优异的电学和力学性能，体积电阻率低至1.11×10-4〇·cm，粘接Si-Ag、Ni-Ni、Au-Au、Cu-Cu和Ag-Ag界面的芯片剪切强度分别为36.17、33.38、30.22、18.01和11.07 kgf，可与市售进口导电银胶性能相媲美。此外，研究发现可以通过微调导电银胶配方的方法，来改善不同材料界面粘接的力学性能。
The influence of important factors such as silver powder type,curing agent type and dosage,and accelerator type on the electrical and mechanical properties of conductive silver adhesive was studied and analyzed in this article,and the mechanical properties of conductive silver adhesive bonding at different interfaces were evaluated and analyzed. Finally,the one-component conductive silver adhesive with the long room temperature applicability period was prepared with the silver powder loading of 80%,the melamine curing agent added to the resin of 8.3%,and the composite promoter selected.The research results showed that,the conductive silver adhesive had excellent electrical and mechanical properties,with the volume resistivity as low as 1.11×10-4 〇·cm.The chip shear strength for bonding Si-Ag,Ni-Ni,Au-Au,Cu-Cu,and Ag-Ag interfaces was 36.17,33.38,30.22,18.01,and 11.07 kgf,respectively,which was comparable to the performance of commercially available imported conductive silver adhesive. In addition,it has found that the mechanical properties of interface bonding between different materials could be improved by fine-tuning the conductive silver adhesive formula.
