期刊信息
期刊名称：《中国胶粘剂》CHINA ADHESIVES
创办日期：1986(1973)
主管部门：上海华谊（集团）有限公司
主办单位：上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会
刊 期：月刊
电 话：010-87663098/87663304
Email：GXLJ@chinajournal.net.cn
国内统一刊号(CN)：
CN 31-1601/TQ
国际标准刊号(ISSN)：
ISSN 1004-2849
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本刊介绍
《中国胶粘剂》为重点报道中国胶粘剂科研成果和最新进展的学术期刊，月刊。1973年创刊，原名为《树脂粘合剂》，1979年更名为《粘合剂》，1991年更名为《中国胶粘剂》，2014年12月，成为原国家新闻出版广电总局第一批认定学术期刊。
主管单位是上海华谊控股集团有限公司，主办单位是上海市合成树脂研究所有限公司、中国胶粘剂和胶粘带工业协会。
期刊在国内外公开发行，国内发行代号为4-454，国外发行代号为M5121；国内统一连续出版物号为CN31-1601/TQ，国际标准连续出版物号为ISSN 1004-2849。
期刊设有专题综述、研究报告、工艺与应用、材料科学等栏目，主要报道国内外胶粘剂、密封剂和胶粘带行业的最新理论研究成果、原料/设备/制备工艺创新、粘接接头设计制备技术、生产应用实践等论文和综述等，主要涉及领域主要包括化工、轻工、包装、纺织、建筑、机械、电子、航空、航天、汽车、船舶、林木、家具和印刷等领域。
期刊为中国科技核心期刊、RCCSE中国核心学术期刊，《科技期刊世界影响力指数（WJCI）报告》收录期刊，曾为全国中文核心期刊（2007/2011/2014/2017年），现被“中国核心期刊数据库、”“中国期刊全文数据库”、“中国学术期刊综合评价数据库”、《中国学术期刊影响因子年报》统计源、美国《化学文摘》（CA）、中国知网数据库（CNKI）、万方数据库、维普数据库、新华网“学术中国”以及长江文库等收录，先后荣获《CAJ-CD规范》执行优秀期刊、全国石油和化工行业优秀期刊二等奖、全国石油和化工行业优秀期刊一等奖、华东地区优秀期刊奖、上海市科技期刊审读优秀奖、上海市期刊编校质量优秀奖、全国石油和化工学术期刊50强、全国石油和化工行业期刊100强、全国石油和化工学术期刊60强。2024年，期刊还被中国化工学会发布的首版《化工领域高质量科技期刊分级目录》入选为T3级期刊，标志着我刊已进入化工领域“国内外重要、为学术界所认可的期刊”队列。2024年期刊复合影响因子为1.595，综合影响因子为1.309。
《中国胶粘剂》杂志是胶粘剂行业的窗口，是胶粘剂企业的桥梁，是胶粘剂读者的纽带。
易加工双马来酰亚胺树脂的分子设计与应用
Molecular design and application of easily processable bismaleimide resin
张丹丹;刘彩召;邢文旭;于鸿鑫;张斌;孙明明; Zhang Dandan;Liu Caizhao;Xing Wenxu;Yu Hongxin;Zhang Bin;Sun Mingming;本文系统综述了易加工双马来酰亚胺(BMI)树脂的最新研究进展,重点阐述了改善其加工性能的分子设计与复合改性策略。针对传统BMI树脂存在的熔点高、溶解性差、熔体黏度大及韧性不足等问题,通过在主链中引入柔性脂肪链段、大体积侧基(如芴基、酚酞结构)或功能基团(如DOPO),设计新型BMI单体,可有效降低结晶度、拓宽加工窗口、提升溶解性和韧性。同时,采用共混与共聚改性方法,包括与烯丙基化合物、二元胺扩链以及环氧树脂(EP)、氰酸酯(CE)、苯并噁嗪(BOZ)等其他高性能树脂复合,能够显著优化BMI树脂的熔体流动性、固化行为和综合性能。最后,对易加工BMI树脂的发展前景进行了展望,旨在为开发高性能、高工艺适应性的先进树脂基复合材料提供理论参考和技术指导。
The latest research progress on easily processable bismaleimide(BMI) resin was systematically reviewed in this article,with a focus on molecular design and composite modification strategies to improve its processing performance.To address the issues of traditional BMI resin,such as high melting point,poor solubility,high melt viscosity,and insufficient toughness,novel BMI monomers were designed by introducing flexible aliphatic segments,bulky side groups(such as fluorenyl groups,phenolphthalein structures),or functional groups(such as DOPO) into the main chain,as well as designing new BMI monomer,which could effectively reduce the crystallinity,broaden the processing window,and enhance the solubility and toughness. Meanwhile,the use of blending and copolymerization modification methods,including compounding with allyl compounds,diamine chain extension,and other high-performance resins such as epoxy resin(EP),cyanate ester(CE),and benzoxazine(BOZ),could significantly optimize the melt flowability,curing behavior,and comprehensive performance of BMI resin. Finally,the development prospects of easily processable BMI resin were discussed,aiming to provide theoretical reference and technical guidance for the development of advanced resin-based composites with high performance and high process adaptability.
基于分子结构视角的双马来酰亚胺改性研究进展与展望
Research progress and prospects of bismaleimide modification from the perspective of molecular structure
毕瑞;陆佳莹;汪显;张雪平;范和平; Bi Rui;Lu Jiaying;Wang Xian;Zhang Xueping;Fan Heping;Haiso Electronic Materials (Wuhan) Ltd.;双马来酰亚胺(BMI)作为关键的高性能树脂,在电子信息、航空航天等领域具有重要应用。但BMI多数仅能溶于有毒的强极性溶剂,且存在固化温度高、固化后脆性大等缺点,极大地限制其应用,因此对BMI的改性成为目前研究的重点。本文从分子结构设计角度出发,系统阐述了四类主要改性路径:二元胺扩链改性,通过降低交联密度与引入刚性基团实现韧性与耐热性的协同提升;桥键内扩链改性,借助不同桥键结构(如脂肪族、脂环族、芴基Cardo等)显著改善BMI溶解性与综合性能;功能性基团引入,通过N-取代、芳环取代或末端引入烯丙基、磷氧基、硅氧基等基团,定向赋予BMI阻燃、低介电、高韧性等特性;共聚/共混改性,利用多元协同效应,通过与环氧树脂、聚酰亚胺等复合,构建多组分交联网络,实现性能的集成优化。最后,在总结中指出当前改性研究中面临的性能平衡、工艺适配与环保性等挑战,并希望通过多重策略协同、生物基改性剂开发及绿色溶剂体系构建等途径,推动BMI在高端领域向高性能、多功能和可持续方向发展。
Bismaleimide(BMI),as a key high-performance resin,has significant applications in fields such as electronic information,aerospace,and others.However,most BMI resins can only dissolve in toxic,strongly polar solvents,and have drawbacks such as high curing temperature and high brittleness after curing,which greatly limit their application. Therefore,the modification of BMI has become a major focus of current research. From the perspective of molecular structure design,four main modification approaches were systematically elaborated in this paper.Diamine chain-extension modification achieved a synergistic improvement in toughness and heat resistance by reducing crosslinking density and introducing rigid groups.Bridge-bond internal chain-extension modification significantly improved the solubility and comprehensive properties of BMI through different bridge-bond structures(such as aliphatic,alicyclic,fluorenyl-based Cardo,etc.).Introduction of functional groups,such as N-substitution,aromatic ring substitution,or terminal introduction of allyl,phosphorus-oxygen,silicon-oxygen groups,imparted targeted properties to BMI such as flame retardancy,low dielectric constant,and high toughness.Copolymerization/blending modification utilized multi-component synergistic effect,constructing multi-component crosslinked networks by compounding with epoxy resins,polyimides,to achieve integrated optimization of performance.Finally,in the summary,it was pointed out that current modification research faced challenges such as balancing properties,process compatibility,and environmental friendliness. It was also expressed that through multiple synergistic strategies,the development of bio-based modifiers,and the construction of green solvent systems,BMI could be promoted towards high performance,multifunctionality,and sustainability in high-end fields.
改性沥青多因素耦合老化机理及表征评价研究综述
A review on the multi-factor coupled aging mechanism of modified asphalt and its characterization evaluation
徐博;肖凤;张浩明;王志祥; Xu Bo;Xiao Feng;Zhang Haoming;Wang Zhixiang;改性沥青在热、氧、紫外线及水分等多因素耦合作用下的老化行为,是决定沥青路面耐久性的关键。本文系统综述了其老化机理,阐述了热氧协同、光化学降解与水侵蚀等过程的相互作用。在表征方法方面,分析了四组分分析、光谱、色谱及显微技术等在揭示化学组分、分子结构与微观形貌演变中的应用与局限。研究指出,现有评价多基于高温、低温及疲劳等宏观性能,并逐步与微观表征相结合。然而,当前研究在模拟条件真实性、多因素协同机制的定量解析以及微观-宏观跨尺度关联方面仍显不足。未来需构建更贴近实际服役环境的耦合老化试验方法,从分子尺度深化机理认识,并建立统一的多尺度性能评价体系,从而为提升路面使用寿命提供理论依据与技术支撑。
The aging behavior of modified asphalt under the coupled effects of multiple factors such as heat,oxygen,ultraviolet radiation,and moisture is crucial for determining the durability of asphalt pavement.Its aging mechanism was systematically reviewed in this article,and the interactions among processes such as thermal-oxidative synergism,photochemical degradation,and water erosion were elucidated. In terms of characterization methods,the application and limitations of four component analysis,spectroscopy,chromatography,and microscopy techniques in revealing chemical composition,molecular structure,and microstructural evolution were analyzed.Research indicated that existing evaluations were mostly based on macroscopic properties such as high temperature,low temperature,and fatigue,and were gradually combined with microscopic characterization. However,current research still showed deficiencies in simulating the authenticity of conditions,quantitatively analyzing the multi-factor synergistic mechanisms,and establishing micro-macro cross-scale correlations. In the future,it was necessary to establish a coupled aging test method that was more closely aligned with actual service environments,deepened mechanistic understanding at the molecular scale,and established a unified multi-scale performance evaluation system,in order to provide theoretical basis and technical support for enhancing the service life of pavements.
固化型丙烯酸酯压敏胶的制备与性能研究
Study on preparation and properties of curable acrylate pressure sensitive adhesive
宫菲;薛刚;张绪刚;孙明明;刘彩召;王磊;李坚辉;张斌; Gong Fei;Xue Gang;Zhang Xugang;Sun Mingming;Liu Caizhao;Wang Lei;Li Jianhui;Zhang Bin;针对传统压敏胶粘接强度有限,而高强度结构胶施工复杂的问题,本研究采用丙烯酸酯软、硬单体和含羧基官能单体,通过溶液聚合法合成丙烯酸酯压敏胶液。以乙酰丙酮铝(AlACA)作为交联剂,并引入环氧树脂和潜伏型固化剂,研制出一种固化型丙烯酸酯压敏胶。系统研究了各组分及工艺对其固化前压敏性能(初粘力、180°剥离强度、持粘力)与固化后高强度性能(剪切强度、90°剥离强度)的影响。研究结果表明:确定了较优质量配比为,m(丙烯酸酯压敏胶液)∶m(AlACA溶液)∶m(F-44型环氧树脂)∶m(潜伏型固化剂)=100∶1.5∶30∶1.5。在此配比下,固化型丙烯酸酯压敏胶在固化前后均表现出优异的粘接性能。该胶膜实现了无需外部加压的简易施工与高强度固化的结合,适用于对施工便捷性和粘接强度均有要求的领域。
In response to the limited bonding strength of traditional pressure sensitive adhesive and the complex construction of high-strength structural adhesive,acrylate pressure sensitive adhesive solution was synthesized in this study through solution polymerization using acrylic soft and hard monomers and carboxyl functional monomers.A curable acrylate pressure sensitive adhesive was developed using aluminum acetylacetonate(AlACA) as the crosslinking agent and incorporating epoxy resin and latent curing agent. The effects of various components and processes on pressure sensitive properties before curing(initial tack,180° peel strength,holding power) and high-strength properties after curing(shear strength,90° peel strength) were systematically studied.The research results showed that the optimal mass ratio was determined as follows,m(acrylate pressure sensitive adhesive solution)∶m(AlACA solution)∶m(F-44 epoxy resin)∶m(latent curing agent)=100∶1.5∶30∶1.5.Under this ratio,the curable acrylate pressure sensitive adhesive exhibited excellent bonding properties before and after curing. This adhesive film achieved a combination of simple construction without external pressure and high-strength curing,suitable for fields that required both construction convenience and bonding strength.
耐电解液高性能丙烯酸酯压敏胶的研制
Development of electrolyte resistance high-performance acrylate pressure sensitive adhesive
李铭杰;李健雄; Li Mingjie;Li Jianxiong;针对锂离子电池用胶带在电解液环境中易失效的问题,本研究通过单因素试验,采用丙烯酸异辛酯(2-EHA)和甲基丙烯酸月桂酯(LMA)为长链软单体,甲基丙烯酸甲酯(MMA)为硬单体,甲基丙烯酸(MAA)和丙烯酸羟乙酯(HEA)为功能单体,甲基丙烯酸缩水甘油酯(GMA)为自交联单体,偶氮二异丁腈(AIBN)和过氧化二苯甲酰(BPO)为引发剂,乙酸乙酯为溶剂,制备了一款耐高温、耐电解液性能优异的溶剂型高性能丙烯酸酯压敏胶。系统探讨了长链软单体、功能单体、引发剂、自交联单体和固化剂的用量对压敏胶的黏度、180°剥离力、耐高温性能和耐电解液性能的影响。研究结果表明:对于耐电解液高性能丙烯酸酯压敏胶,长链软单体的用量、功能单体的用量对压敏胶的180°剥离力性能影响较大,自交联单体能显著提高压敏胶的内聚强度、耐高温和耐电解液性能。当长链软单体占比为79.5%、功能单体为4%、引发剂为0.6%、自交联单体为1.5%、固化剂为胶液质量的0.8%时,所制备的压敏胶综合性能较优,其黏度适中,180°剥离力为14.1 N/25 mm,并同时具备良好的耐高温性能与耐电解液性能。由上述高性能丙烯酸酯压敏胶制备的耐电解液胶带产品可应用于动力电池、储能电池、消费电子电池等产品,耐电解液性能达到电池产品的性能要求。
To address the issue of adhesive tape for lithium-ion battery easily failing in electrolyte environments,a solvent-based high-performance acrylate pressure sensitive adhesive with excellent high temperature resistance and electrolyte resistance was prepared in this study through single-factor experiments.The formulation included isooctyl acrylate(2-EHA) and lauryl methacrylate(LMA) as long-chain soft monomers,methyl methacrylate(MMA) as hard monomer,methacrylic acid(MAA) and hydroxyethyl acrylate(HEA) as functional monomers,glycidyl methacrylate(GMA) as self-crosslinking monomer,azobisisobutyronitrile(AIBN) and benzoyl peroxide(BPO) as initiators,and ethyl acetate as solvent.The effects of the dosage of long-chain soft monomers,functional monomers,initiators,self-crosslinking monomer,and curing agents on the viscosity,180° peel force,high temperature resistance,and electrolyte resistance of pressure sensitive adhesive were explored systematically. The research results showed that for electrolyte resistance high-performance acrylate pressure sensitive adhesive,the amount of long-chain soft monomers and functional monomers had a significant impact on the 180° peel force performance of pressure sensitive adhesive. Self-crosslinking monomer could significantly improve the cohesive strength,high temperature resistance,and electrolyte resistance of pressure sensitive adhesive.When the proportion of long-chain soft monomers was 79.5%,the proportion of functional monomers was 4%,the initiators was 0.6%,the self-crosslinking monomer was 1.5%,and the curing agent was 0.8% of the adhesive solution mass,the comprehensive performance of the prepared pressure sensitive adhesive was excellent. Its viscosity was moderate,the 180° peel force was 14.1 N/25 mm,and it also had good high temperature resistance and electrolyte resistance.The electrolyte resistance adhesive tape product prepared from the high-performance acrylate pressure sensitive adhesive mentioned above could be applied to power batteries,energy storage batteries,consumer electronics batteries,and other products,meeting the performance requirements of battery products in terms of electrolyte resistance.
不同化学体系热熔胶在平滑铝护套高压电缆中的适用性研究
Applicability of hot melt adhesive with different chemical systems in smooth aluminum-sheathed high-voltage cables
陈嘉威;周宏;周韫捷;邵悦;李垠阅;刘英; Chen Jiawei;Zhou Hong;Zhou Yunjie;Shao Yue;Li Yinyue;Liu Ying;State Grid Shanghai Cable Company;平滑铝护套高压交联聚乙烯电缆具有电气接触性能好、传输容量大、外径小、重量轻等优点,但在机械性能方面存在不足,需要通过热熔胶将铝护套和外护层(通常采用聚乙烯或聚氯乙烯材料)牢固粘接进行改善,因此,亟需开展针对电缆实际应用需求的热熔胶关键性能研究。本论文以初步筛选的4种不同化学体系的热熔胶为研究对象,首先进行红外光谱分析和热性能测试,确定基本成分和熔融温度;之后,将4种热熔胶应用于聚乙烯(PE)、聚氯乙烯(PVC)和铝片,制备粘接试样;最后,测试常温、90℃稳态温升及180℃短时温升条件下试样的T-剥离强度及拉伸剪切强度,据此分析4种热熔胶在分别采用PE和PVC外护层的平滑铝护套高压电缆中的适用性。研究结果表明:(1)PE热熔胶与PE材料相容性良好,其弹性模量约为316.0 MPa,熔点约为128℃,室温下T-剥离强度和拉伸剪切强度分别为3.39 N/mm和5.91 MPa,90℃稳态温升条件下分别下降为2.63 N/mm和2.31 MPa,180℃短时热处理后参数值略有升高,上述各项性能参数均满足采用PE外护层的平滑铝护套电缆应用需求。(2)在应用于PVC材料时,4种热熔胶的粘接效果均不佳,其中PEVA热熔胶的粘接性能在室温下相对最优,T-剥离强度为1.56 N/mm,拉伸剪切强度为3.05 MPa,但其熔融温度仅为58.84℃,仍无法满足电缆运行温度要求。(3)基于本文测试结果,对于平滑铝护套高压交联聚乙烯电缆的热熔胶选型建议为:采用PE外护层时,应优先选用高熔融温度的PE热熔胶,其在常温和暂态高温下均能保持优异的粘接强度与稳定性;采用PVC外护层时,则需进一步开发或寻找熔融温度更高且与PVC极性相匹配的新型热熔胶体系。
Smooth aluminum-sheathed high-voltage cross-linked polyethylene cables have advantages such as excellent electrical contact performance,large transmission capacity,small outer diameter,and light weight.However,they have deficiencies in mechanical properties,which need to be improved by firmly bonding the aluminum sheath to the outer protective layer(typically made of polyethylene or polyvinyl chloride) with hot melt adhesive.Therefore,there is an urgent need to conduct research on the key properties of hot melt adhesive tailored to the practical application requirements of cables.The preliminary screening of four different chemical systems of hot melt adhesive was focused in this paper.Firstly,infrared spectroscopy analysis and thermal performance testing were conducted to determine the basic components and melting temperature.Afterwards,four kinds of hot melt adhesive were applied to polyethylene(PE),polyvinyl chloride(PVC),and aluminum sheets to prepare adhesive samples.Finally,the T-peel strength and tensile shear strength of the samples were tested under normal temperature,steady-state temperature rise of 90 ℃,and short-term temperature rise of 180 ℃.Based on this,the applicability of four kinds of hot melt adhesive in smooth aluminum-sheathed high-voltage cables with PE and PVC outer protective layers was analyzed.The research results showed that,(1) PE hot melt adhesive had good compatibility with PE material,with the elastic modulus of about 316.0 MPa and the melting point of about 128 ℃.At room temperature,the T-peel strength and tensile shear strength were 3.39 N/mm and 5.91 MPa,respectively. Under steady-state temperature rise conditions at 90 ℃,they decreased to 2.63 N/mm and 2.31 MPa,respectively.After short-term heat treatment at 180 ℃,the parameter values slightly increased. All the above performance parameters met the application requirements of smooth aluminum-sheathed cables with PE outer protective layer.(2) When applied to PVC material,the bonding effects of all four kinds of hot melt adhesive were poor.Among them,PEVA hot melt adhesive had relatively the best bonding performance at room temperature,with the T-peel strength of 1.56 N/mm and the tensile shear strength of 3.05 MPa.However,its melting temperature was only 58.84 ℃,which still could not meet the temperature requirements for cable operation.(3) Based on the test results in this paper,the recommended selection of hot melt adhesive for smooth aluminum-sheathed high-voltage cross-linked polyethylene cables was:when using PE outer protective layer,high melting temperature PE hot melt adhesive should be preferred,which could maintain excellent bonding strength and stability at both room temperature and transient high temperature.When using PVC outer protective layer,it was necessary to further develop or search for a new type of hot melt adhesive system with higher melting temperature and matching PVC polarity.
