DCOIT microcapsules prepared by gelatin/gum arabic composite coacervation
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以羟乙基纤维素(HEC)为乳化剂、明胶和阿拉伯胶为壁材、4,5-二氯-2-正辛基-4-异噻唑啉-3-酮(DCOIT)芯材、甲醛为固化剂、冰醋酸(HAc)和氢氧化钠(NaOH)为pH值调节剂,采用复合凝聚法制备了DCOIT微胶囊。通过单因素试验法探讨了壁材浓度、壁芯比、反应时间、pH值、搅拌速率和乳化剂类型等对微胶囊的粒径、稳定性和包埋率等影响。结果表明:当w(壁材)=3%、壁芯比=m(壳层单体)/m(核层单体)=3、反应时间为2 h、pH≤4.5和搅拌速率为1 000 r/min时,相应DCOIT微胶囊的性能相对最佳。
Abstract：With hydroxyethyl cellulose(HEC) as emulsifier,gelatin and gum arabic as shell-material,4,5- dichloro-2-octyl-4-isothiazoline-3-ketone(DCOIT) as core-material,formaldehyde as curing agent,acetic acid(HAc) and NaOH as regulators of pH value,a DCOIT microcapsule was prepared by composite coacervation. The influences of shell concentration,shell/core rate,reaction time,pH value,mix round speed and emulsifier type on particle size,stability,and embedding rate of microcapsule were discussed by single-factor experiment method. The results showed that the corresponding DCOIT microcapsule had the reversely best properties when mass fraction of shell-material was 3%,the shell/core ratio or mass ratio of m(shell monomers )/m(core monomers) was 3,reaction time was 2 h,pH was not more than 4.5,and mix round speed was 1 000 r/min.
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基本信息:
DOI：10.13416/j.ca.2012.06.004
中图分类号:TQ07
引用信息:
[1]胡剑青,李辉,涂伟萍,等.明胶/阿拉伯胶复合凝聚法制备DCOIT微胶囊[J].中国胶粘剂,2012,21(06):31-34+52.DOI:10.13416/j.ca.2012.06.004.
Citation Information:
[1]Hu Jianqing,Li Hui,Tu Weiping,Wang Feng (College of Chemistry and Chemical Engineering,South China University of Technology, Guangzhou 510640,China).DCOIT microcapsules prepared by gelatin/gum arabic composite coacervation[J].中国胶粘剂,2012,21(06):31-34+52.DOI:10.13416/j.ca.2012.06.004.
基金信息:
国家自然科学基金资助项目(50903031); 广东省教育厅学科建设专项资金项目(N9100240)
2012-06-30
2012-06-30