Preparation of platinum catalysts for addition siicone rubber and their catalysis activity
| 1,440 | 67 | 9 |
| 下载次数 | 被引频次 | 阅读次数 |
合成了几种不同的铂催化剂 (氯铂酸二乙烯基四甲基二硅氧烷 ,氯铂酸 -异丙醇 ,氯铂酸 -邻苯二甲酸二乙酯 )。考察了其对于有机硅橡胶加成聚合反应的催化活性 ,并从催化机理的角度初步探讨了催化剂不同活性差异的原因
Abstract:Three kinds of catalyst (chloroplatinic acid isopropanol, chloroplatinic acid M Vi M Vi , chliroplatinic acid diethyl o phthalate) are synthesized. Among these three kinds of catalyst, chloroplatinic acid M Vi M Vi has the highest activity and chloroplatinic acid isopropanol has the lowest activity, chloroplatinic acid diethyl o phthalate's activity is ranged between the above two kinds of catalyst. The reason that the catalyst has different activity is discussed by catalysis mechanism.
[1] 谭必恩,潘慧铭,王卫星,张廉正.加成型有机硅橡胶研究进展[J],合成橡胶工业,1999(3).
[2] 谭必恩,潘慧铭,张廉正,赵飞明.工业中铂催化剂研究进展[J].宇航材料工艺,1999(3).
[3] KARSTEDTBD .USP 3775452,1973.
[4] 黄文润.有机硅材料的市场与产品开发(续八)[J].有机硅材料及应用,1994,(1):1.
[5] LEWISLN ,URIARTERJ .LEWISN .J.Catal.1991,127:105.
[6] LEWISLN ,LEWISN .Chem.Mater.,1989,1:106.
[7] LEWISLN ,URIARTERJ.Organometallics.1990,9:621.
基本信息:
中图分类号:O643.3
引用信息:
[1]谭必恩,赵华,潘慧铭.加成型硅橡胶铂催化剂的制备及其活性研究[J].中国胶粘剂,2001(04):1-4.
Citation Information:
[1]TAN Bien 1, ZHAO Hua 2, PAN Hui ming 3 (1 Beijing Institute of Aeronautic Materials Beijing 100095, China, 2 Enshi College of Profession Technology, Hubei 445000, China, 3. Material Science and Engineering College, Guangzhou 510641, China).Preparation of platinum catalysts for addition siicone rubber and their catalysis activity[J].中国胶粘剂,2001(04):1-4.
2001-07-30
2001-07-30