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2024, 05, v.33 11-18+24
生物基高分子改性沥青研究进展
基金项目(Foundation): 陕西省重点研发计划(2024GX-YBXM-371); 陕西省交通科技项目(17-06K)
邮箱(Email): zhangzp1999@163.com;
DOI: 10.13416/j.ca.2024.05.007
摘要:

随着我国道路桥梁建设的蓬勃发展,改性沥青逐渐占领应用市场,在沥青中掺加环氧树脂、聚氨酯、酚醛树脂等高分子可获得高性能的改性沥青或沥青混合料。为了减少对不可再生资源的消耗,以便于道路工程的可持续发展,生物基原料逐渐替代石油基原料。本文针对树脂类(生物基聚氨酯、生物基酚醛树脂)改性沥青、生物基橡胶改性沥青、生物基天然弹性体改性沥青、生物基复合型改性沥青等原料和研究进展进行了梳理和汇总,并对生物基改性剂(植物油、植物酚、木质素、松香和衣康酸等)最新研究成果进行分享。提出了生物基高分子改性沥青目前存在的问题,最后对其未来发展进行了展望。

Abstract:

With the vigorous development of China's road and bridge construction,modified asphalt gradually occupies the application market,and adding high polymers such as epoxy resin,polyurethane,phenolic resin to asphalt can obtain high-performance modified asphalt or asphalt mixture. In order to reduce the consumption of non-renewable resources and facilitate the sustainable development of road engineering,bio-based raw materials are gradually replacing petroleum-based raw materials.In this paper,the raw materials and research progress of resin modified asphalt(bio-based polyurethane,bio-based phenolic resin),bio-based rubber modified asphalt,bio-based natural elastomer modified asphalt,and bio-based composite modified asphalt were mainly reviewed and summarized,and the latest research results of bio-based modifiers(plant oil,plant phenols,lignin,rosin,itaconic acid,etc.) were also shared. The current problems of bio-based polymer modified asphalt were proposed,and finally,the future development prospects were discussed.

参考文献

[1]肖凤,邓星鹤.沥青改性剂研究进展[J].中国胶粘剂,2020,29(9):61-66.

[2]黄彬,马丽萍,许文娟.改性沥青的研究进展[J].材料导报,2010,24(1):137-141.

[3]杨宇,王洪国,廖克俭,等.环保型SBS改性阻燃沥青性能研究[J].石油炼制与化工,2016,47(3):31-35.

[4]马松琪,刘小青,朱锦.生物基环氧树脂的研究进展[J].粘接,2014,35(6):43-49.

[5]张东辉.生物基酚醛树脂的制备与性能研究[D].西安:长安大学,2017.

[6] LU Q,XIN C,ALAMRI M,et al. Development of porous asphalt mixture with bio-based epoxy asphalt[J].Journal of Cleaner Production,2021,317:28404.

[7] UCHOA A F J,ROCHA W S,FEITOSA J P M,et al.Exploiting epoxidized cashew nut shell liquid as a potential bio-additive to improve asphalt binder performance[J].Journal of Cleaner Production,2021,314:128061.

[8] GAUDENZI E,CARDONE F,LU X H,et al. Performance assessment of asphalt mixtures produced with a bio-binder containing 30%of lignin[J]. Materials and Structures,2022,55(8):1-13.

[9]刘虓嵩,张增平,郭茵霄,等.用于公路工程的聚氨酯密封胶研究进展[J].中国胶粘剂,2023,32(9):49-57.

[10]夏磊.聚氨酯改性沥青的性能研究[D].青岛:中国石油大学(华东),2016.

[11] MENG Y Y,ZHAN L,HU C C,et al. Research on modification mechanism and performance of an innovative bio-based polyurethane modified asphalt:A sustainable way to reducing dependence on petroleum asphalt[J].Construction and Building Materials,2022,350:128830.

[12] MOHAMMADJAVAD K,ABBAS M,AHMAD G,et al.Introducing a sustainable bio-based polyurethane to enhance the healing capacity of bitumen[J]. Journal of Materials in Civil Engineering,2022,34(3):1-12.

[13] CUADRI A A,GARCíA-MORALES M,NAVARRO F J,et al. Processing of bitumens modified by a bio-oilderived polyurethane[J].Fuel,2014,118:83-90.

[14] ALIABADI A A,THOMSON M J,WALLACE J S,et al.Efficiency and emissions measurement of a stirlingengine-based residential microcogeneration system run on diesel and biodiesel[J]. Energy&Fuels,2009,23(2):1032-1039.

[15] LI Y M,LV C Y,CHENG P F,et al. Application of bioresin in road materials:Rheological and chemical properties of asphalt binder modified by lignin-phenolic resin[J].Case Studies in Construction Materials,2023,18:e01989.

[16]张林艳,王磊,马永,等.天然橡胶改性沥青研究应用与展望[J].应用化工,2022,51(2):582-586.

[17] FARDZANELA S,TONY P,NICK T,et al. Engineering characterization and environmental analysis of natural rubber latex modified asphalt mixture[J].Construction and Building Materials,2023,402:132970.

[18] YAN Y,GUO R X,CHENG C,et al. Viscosity prediction model of natural rubber-modified asphalt at high temperatures[J].Polymer Testing,2022,113:107666.

[19] YAN S,GUO N,CHU Z,et al. A study of molecular dynamic simulation and experimental performance of the eucommia ulmoides gum-modified asphalt[J]. Materials,2023,16(16):5700.

[20]王润国,孙超英,安晓鹏,等.生物基弹性体的研究进展[J].橡胶工业,2023,70(9):675-685.

[21]王枫成.复合改性沥青性能研究[J].中国胶粘剂,2020,29(7):54-57.

[22]王立志,毕飞,赵品晖.聚合物改性沥青流变性能研究进展[J].山东建筑大学学报,2018,33(6):56-62.

[23] SUN J,ZHANG Z P,YE J,et al. Preparation and properties of polyurethane/epoxy-resin modified asphalt binders and mixtures using a bio-based curing agent[J].Journal of Cleaner Production,2022,380(P1):135030.

[24] WANG Z,ZHANG X,WANG R G,et al. Synthesis and characterization of novel soybean-oil-based elastomers with favorable processability and tunable properties[J].Macromolecules,2012,45(22):9010-9019.

[25] CAO D W,TAN H,YANG Z,et al. Research on performance of natural rubber latex composite-modified asphalt[J].Journal of Testing and Evaluation,2022,50(4):1962-1976.

[26]何明,马黎倩,马宏明,等.蓖麻油基多元醇的制备及对环氧树脂的增韧改性[J].化工新型材料,2015,43(4):185-187.

[27] HU F S,YADAV S K,SCALA J J L,et al. Epoxidized soybean oil modified using fatty acids as tougheners for thermosetting epoxy resins:Part 1[J]. Journal of Applied Polymer Science,2021,138(24):50570.

[28] STIRNA U,LAZDI?A B,VILSONE D,et al. Structure and properties of the polyurethane and polyurethane foam synthesized from castor oil polyols[J]. Journal of Cellular Plastics,2012,48(6):476-488.

[29] LIU J,LV S,PENG X H,et al. Improvements on performance of bio-asphalt modified by castor oil-based polyurethane:An efficient approach for bio-oil utilization[J]. Construction and Building Materials,2021,305:124784.

[30]赵晓磊,侯桂香,于守武.植物酚型生物基环氧树脂研究进展[J].高分子材料科学与工程,2022,38(9):167-175.

[31] LIU T,HAO C,ZHANG S,et al. A Self-healable high glass transition temperature bioepoxy material based on vitrimer chemistry[J]. Macromolecules,2018,51(15):5577-5585.

[32]张佳良.基于香草醛的生物基可降解聚氨酯的制备及其性能研究[D].吉林:长春工业大学,2022.

[33] LIU T,HAO C,WANG L W,et al. Eugenol-derived biobased epoxy:Shape memory,repairing,and recyclability[J].Macromolecules,2017,50(21):8588-8597.

[34]贾犇.阻燃型聚氨酯复合注浆材料的研究[D].太原:太原理工大学,2022.

[35] ZHANG D Y,LIU X H,BAI X F,et al. Phthalonitrileetherified cardanol-phenol-formaldehyde resin:Synthesis,characterization and properties[J]. Pigment&Resin Technology,2022,51(6):609-617.

[36]李心祥.木质素基聚氨酯的合成及性能研究[D].无锡:江南大学,2022.

[37] XIE J,SUN H,YANG Y C,et al. Preparation of hightoughness lignin phenolic resin biomaterials based via polybutylene succinate molecular intercalation[J].International Journal of Molecular Sciences,2023,24(7):6418.

[38] GULFER B M,SEREF O,HACER Y. Physical and microstructural properties of new boron resin compound synthesized asphalt[J]. Journal of Materials in Civil Engineering,2023,35(2):4022426.

[39]雷小磊,崔玉龙.松香树脂改性沥青胶浆路用性能试验研究[J].西昌学院学报(自然科学版),2021,35(2):58-62.

[40]王阳,张欢欢,解鸿宇,等.衣康酸酯基聚氨酯乳液的制备及其性能[J].青岛科技大学学报(自然科学版),2018,39(S1):41-45;48.

[41]李鹏.基于衣康酸和大豆油的环保型光固化涂料的研究[D].太原:中北大学,2016.

[42] WANG R G,MA J,ZHOU X X,et al. Design and preparation of a novel cross-linkable,high molecular weight, and bio-based elastomer by emulsion polymerization[J]. Macromolecules,2012,45(17):6830-6839.

基本信息:

DOI:10.13416/j.ca.2024.05.007

中图分类号:U414

引用信息:

[1]田培军,阚士云,张增平,等.生物基高分子改性沥青研究进展[J].中国胶粘剂,2024,33(05):11-18+24.DOI:10.13416/j.ca.2024.05.007.

基金信息:

陕西省重点研发计划(2024GX-YBXM-371); 陕西省交通科技项目(17-06K)

发布时间:

2024-05-30

出版时间:

2024-05-30

引用

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