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2008, 04, 64-70
New generation of Vinavil~ w/b polymer adhesives ——beyond wood failure
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摘要:

One of the most relevant feature of water based thermoplastic adhesives employed in not bearing hard wood structure is to obtain final joints with both higher mechanical properties than wood it self and creep resistance. Mechanical performance is related to the affinity between adhesive and substrate and it can be influenced by wood type,while the wood joint resistance to static load is affected by mechanical properties of the adhesive it self. Two classes of polymers with similar chemical composition,but synthesized in different ways were chosen,characterized using spectroscopic,calorimetric and morphological analysis and tested as adhesives according to international standards[1-2].Interestingly,they showed dramatic differences in the shear test: one class caused substrate cohesive failure,while the second showed a superficial adhesive detaching. Consequently correlation between different mechanical properties showed by the polymer tested and the adhesion mechanism involved were high lighted. In this way a new generation of Vinavil w/b polymer adhesive were synthesized and specific performances are put in evidence by the adoption of novel and promising technique that allows to "go beyond" traditional standards.

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Abstract:

One of the most relevant feature of water based thermoplastic adhesives employed in not bearing hard wood structure is to obtain final joints with both higher mechanical properties than wood it self and creep resistance. Mechanical performance is related to the affinity between adhesive and substrate and it can be influenced by wood type,while the wood joint resistance to static load is affected by mechanical properties of the adhesive it self. Two classes of polymers with similar chemical composition,but synthesized in different ways were chosen,characterized using spectroscopic,calorimetric and morphological analysis and tested as adhesives according to international standards[1-2].Interestingly,they showed dramatic differences in the shear test: one class caused substrate cohesive failure,while the second showed a superficial adhesive detaching. Consequently correlation between different mechanical properties showed by the polymer tested and the adhesion mechanism involved were high lighted. In this way a new generation of Vinavil w/b polymer adhesive were synthesized and specific performances are put in evidence by the adoption of novel and promising technique that allows to "go beyond" traditional standards.

参考文献

[1]ISO6238-2001,Adhesives-wood-to-wood bonds-determination ofshear strength bycompressive loading[S].

[2]DIN EN14256-2007,Adhesives for non-structural wood applications-Test method and requirements for resistance to static load[S].

[3]BANDELA.Incollare il legno[M].San Giovanni al Natisone:Catas Ed.,1994.

[4]GHOSH S,KRISHNAMURTI N.Protective colloids and their effects on poly(vinyl acetate)emulsion[J].Paint&Ink International,1996,9:19-21.

[5]FINCH CA.Polyvinyl alcohol:Properties and applications[M].NewYork:Wiley,1973.

[6]EGRETH,DIMONIE V L,SUDOLE D,et al.Characterization of grafting in the emulsion polymerization of vinyl acetate using poly(vinyl alcohol)as stabilizer[J].Journal ofApplied Polymer Science,2001,82(7):1739-1747.

[7]SUZUKI A,YANOM,SAIGAT,et al.Studyon the initial stage ofemulsion polymerization ofvinyl acetate using poly(vinyl alcohol)as a protective colloid[J].Colloid&Polymer Science,2003,281(4):337-342.

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中图分类号:TQ430

引用信息:

[1]M.Ripamonti,F.Chiozza,S.Paffumi等.New generation of Vinavil~ w/b polymer adhesives ——beyond wood failure[J].中国胶粘剂,2008(04):64-70.

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