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2024, 06, v.33 1-8
环氧沥青相容性研究进展
基金项目(Foundation): 国家重点研发计划(2017YFE0116000)
邮箱(Email): hfan@zju.edu.cn;
DOI: 10.13416/j.ca.2024.06.003
摘要:

环氧沥青是一种性能优异的改性沥青,主要应用于大跨度桥梁的桥面铺装,具有较为广阔的市场。目前,国内的环氧沥青主要依赖于进口,价格高昂,因此开发出国产环氧沥青是近些年的一个研究热点。由于环氧树脂和沥青的极性差异,如何解决相容性问题是环氧沥青研究的重点之一。本文主要综述了环氧沥青相分离的形成机理、相容性的研究方法以及增容的方法。

Abstract:

Epoxy asphalt is a kind of modified asphalt with excellent performance,which has been mainly used in bridge deck paving of large-span bridges,and has a relatively broad market.At present,domestic epoxy asphalt mainly relies on imports and is very expensive,so developing domestically produced epoxy asphalt has been a research hotspot in recent years. Due to the polarity difference between epoxy resin and asphalt,solving compatibility issues is one of the focuses of epoxy asphalt research. In this article,the formation mechanism,compatibility research methods,and compatibilization methods of epoxy asphalt phase separation were mainly reviewed.

参考文献

[1]肖凤,邓星鹤.沥青改性剂研究进展[J].中国胶粘剂,2020,29(9):61-66.

[2]宋乐春,宁爱民,李志军,等.聚合物改性沥青性能研究[J].中国胶粘剂,2018,27(4):31-34.

[3]肖凤,邓星鹤. GNPs/SBR复合改性沥青的制备及性能研究[J].中国胶粘剂,2023,32(12):19-27.

[4] XIE H F,LI C X,WANG Q J. A critical review on performance and phase separation of thermosetting epoxy asphalt binders and bond coats[J]. Construction and Building Materials 2022,326(4):126792.

[5] LU Q,BORS J. Alternate uses of epoxy asphalt on bridge decks and roadways[J]. Construction and Building Materials,2015,78:18-25.

[6] HUANG W,QIAN Z,CHEN G,et al. Epoxy asphalt concrete paving on the deck of long-span steel bridges[J].Chinese Science Bulletin,2003,48(21):2391-2394.

[7] LUO S,LU Q,QIAN Z. Performance evaluation of epoxy modified open-graded porous asphalt concrete[J].Construction and Building Materials,2015,76:97-102.

[8] WU P J,HERRINGTON R P,ALABASTER D. Long-term durability of epoxy-modified open-graded porous asphalt wearing course[J]. International Journal of Pavement Engineering 2019,20(8),920-927.

[9]胡青,陈立伟.美国环氧沥青与日本环氧沥青性能对比研究[J].黑龙江交通科技,2010,33(7):43-44.

[10]刘成,李志军,郭皎河,等.热固性环氧沥青相容性研究进展[J].中国胶粘剂,2019,28(4):58-62.

[11] YIN H,ZHANG Y,SUN Y,et al. Performance of hot mix epoxy asphalt binder and its concrete[J]. Materials and Structures,2015,48(11),3825-3835.

[12] XU W,WEI J T,CHEN Z X,et al. Evaluation of the effects of filler fineness on the properties of an epoxy asphalt mixture[J].Materials,2021,14(8):2003.

[13] ZHANG F L,ZHANG L,MUHAMMAD Y,et al. Study on preparation and properties of new thermosetting epoxy asphalt[J].Construction and Building Materials,2021,311:125307.

[14] WANG J,YU X,DING G,et al. Influence of asphalt solvents on the rheological and mechanical properties of cold-mixed epoxy asphalt[J]. Construction and Building Materials,2021,310:125245.

[15] LI Y S,HE L,DU J Z,et al. A novel resourcezation strategy for the alkylphenol distillation residues:From hazardous wastes to high-valued epoxy asphalt materials[J].Journal of Cleaner Production,2023,405:136962.

[16] AI T,XIANG S,WANG Z. Effects of microwave curing on the chemical and physical properties of epoxy asphalt[J].Journal of Materials in Civil Engineering,2016,28(11):06016013.

[17] CABANELAS J C,SERRANO B,GONZALEZ M G,et al.Confocal microscopy study of phase morphology evolution in epoxy/polysiloxane thermosets[J]. Polymer, 2005,46(17):6633-6639.

[18]汪海年,郑文华,尤占平,等.聚合物改性剂和石油沥青相容性评价方法研究进展[J].交通运输工程学报,2023,23(1):8-26.

[19] BAHIA H U,ZHAI H. Storage stability of modified binders using the newly developed LAST procedure[J].Road Materials and Pavement Design,2000,1(1-2):53-73.

[20] NAVARRO F J,PARTAL P,MARTIN'EZ-BOZA F,et al.Thermo-rheological behaviour and storage stability of ground tire rubber-modified bitumens[J]. Fuel,2004,83(14-15):2041-2049.

[21] NASR D,PAKSHIR A H. Rheology and storage stability of modified binders with waste polymers composites[J].Road Materials and Pavement Design,2019,20(4):773-792.

[22] MüLLER M Y,RODRIGUEZ A J. Use of rheological compatibility criteria to study SBS modified asphalts[J].Journal of Applied Polymer Science,2003,90(7):1772-1782.

[23]何颖. SBS改性沥青相态与抗老化性能研究[D].青岛:中国石油大学(华东),2018.

[24]郭皎河,吴晓颖,傅丽,等.不同工艺制备的沥青性能研究[J].中国胶粘剂,2020,29(5):24-28.

[25] TERCJAK A. Phase separation and morphology development in thermoplastic-modified thermosets[M].2017.

[26] LIU Y,ZHANG J,CHEN R,et al. Ethylene vinyl acetate copolymer modified epoxy asphalt binders:Phase separation evolution and mechanical properties[J].Construction and Building Materials,2017,137:55-65.

[27] SU W,HAN X,GONG J,et al. Toughening epoxy asphalt binder using core-shell rubber nanoparticles[J]. Construction and Building Materials,2020,258:119716.

[28] INOUE T. Reaction-induced phase decomposition in polymer blends[J]. Progress in Polymer Science,1995,20(1),119-153.

[29] LIU Y,ZHANG J,JIANG Y,et al. Investigation of secondary phase separation and mechanical properties of epoxy SBS-modified asphalts[J].Construction and Building Materials,2018,165:163-172.

[30] ZHANG J,SU W,LIU Y,et al. Laboratory investigation on the microstructure and performance of SBS modified epoxy asphalt binder[J]. Construction and Building Materials,2021,270:121378.

[31] CHEN R,ZHAO R,LIU Y,et al. Development of ecofriendly fire-retarded warm-mix epoxy asphalt binders using reactive polymeric flame retardants for road tunnel pavements[J]. Construction and Building Materials,2021,284:122752.

[32] SU W,ZHAO R,WANG R,et al. Microstructure and performance of epoxy asphalt binders modified by coreshell rubbers containing different core polymers[J].Construction and Building Materials,2021,304:124689.

[33] JIANG Y,ZHAO R,XI Z,et al. Improving toughness of epoxy asphalt binder with reactive epoxidized SBS[J].Materials and Structures,2021,54:145.

[34] PRADHAN S,PANDEY P,MOHANTY S,et al. Insight on the chemistry of epoxy and its curing for coating applications:A detailed investigation and future perspectives[J].Polymer-Plastics Technology and Engineering,2015,55(8):862-877.

[35]程德金.钢桥面铺装用环氧沥青材料的制备与性能研究[D].西安:长安大学,2017.

[36]周威,赵辉,文俊,等.柔性固化剂对环氧沥青结构和性能影响的研究[J].武汉理工大学学报,2011,33(7):28-31.

[37] ZHANG F L,ZHANG L,GUO X X,et al. Laboratory development and evaluation of an oleylamine curing epoxy asphalt[J].International Journal of Pavement Engineering,2022,24(2):1-10.

[38] LI S,HUANG K,YANG X,et al. Design,preparation and characterization of novel toughened epoxy asphalt based on a vegetable oil derivative for bridge deck paving[J].RSC Advances,2014,4(84):44741-44749.

[39]亢阳,陈志明,闵召辉,等.顺酐化在环氧沥青中的应用[J].东南大学学报(自然科学版),2006(2):308-311.

[40]雷元,胡凯,江亮,等.马来酸酐接枝改性沥青及其动力学研究[J].四川化工,2017,20(2):4-7.

[41]陆学敏,周威,赵辉,等.沥青接枝马来酸酐相容剂的制备及应用研究[J].胶体与聚合物,2011,29(4):168-170;180.

[42]贾辉,陈志明,亢阳,等.高性能环氧沥青材料的绿色制备技术[J].东南大学学报(自然科学版),2008(3):496-499.

[43] SI J,LI Y,WANG J,et al. Improving the compatibility of cold-mixed epoxy asphalt based on the epoxidized soybean oil[J].Construction and Building Materials,2020,243:118235.

[44] YU X,WANG J,SI J,et al. Research on compatibility mechanism of biobased cold-mixed epoxy asphalt binder[J].Construction and Building Materials,2020,250(21):118868.

[45]周威,赵辉,文俊,等.一种高性能环氧沥青增容剂的制备及应用研究[J].湖北大学学报(自然科学版),2012,34(1):81-85.

[46]王丽杰,王月欣,张倩.热固性环氧沥青增容剂的合成及应用研究[J].热固性树脂,2015,30(1):52-56.

[47]吕长亮.环氧沥青的制备与性能研究[D].西安:长安大学,2013.

[48]晏英,肖新颜,刘武,等.有机蒙脱土/环氧树脂复合改性沥青的性能[J].高分子材料科学与工程,2015,31(4):52-56.

[49] ZHAO R,JING F,LI C,et al. Viscosity-curing time behavior,viscoelastic properties,and phase separation of graphene oxide/epoxy asphalt composites[J]. Polymer Composites,2022,43(8):5454-5464.

[50] ZHANG J,WANG R,ZHAO R,et al. Graphene oxidemodified epoxy asphalt bond coats with enhanced bonding properties[J].Materials(Basel),2022,15(19):6846.

基本信息:

DOI:10.13416/j.ca.2024.06.003

中图分类号:U414

引用信息:

[1]钱旦,范宏.环氧沥青相容性研究进展[J].中国胶粘剂,2024,33(06):1-8.DOI:10.13416/j.ca.2024.06.003.

基金信息:

国家重点研发计划(2017YFE0116000)

引用

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